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Synlett 1998; 1998(9): 981-982
DOI: 10.1055/s-1998-1850
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Radical Cyclization of N-Aziridinylimines 4. Highly Efficient Synthesis of dl-Pentalenene via Consecutive Carbon-Carbon Bond Formation Approach

Sunggak Kim* , Jae Ho Cheong, Jimmy Yoo
  • *Department of Chemistry, Korea Advanced Institute of Science and Technology, Taejon 305-701, Korea; Fax + 82 42 8 69 58 20; E-mail: skim@sorak.kaist.ac.kr
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Publication Date:
31 December 2000 (online)

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dl-Pentalenene, an angular triquinane, has been synthesized via tandem radical cyclization of N-aziridinylimine 10 involving the formation of consecutive carbon-carbon bonds.

N-aziridinylimine - tandem radical cyclization - consecutive carbon-carbon bond formation - [6.3.0.04,8]undecane - pentalenene