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Synlett 2000; 2000(2): 201-204
DOI: 10.1055/s-2000-6482
DOI: 10.1055/s-2000-6482
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Heck Reactions Using Aryldiazonium Salts towards Phosphonic Derivatives
Further Information
Publication History
Publication Date:
31 December 2000 (online)
A facile synthesis of aryl vinylphosphonates has been based on Heck reaction of aryldiazonium salts bearing electrowithdrawing or donating groups with vinylphosphonates. A one-pot procedure consisting of Heck reaction and hydrogenation permits the clean formation of useful Wadsworth-Emmons reagents.
Heck reaction - palladium - arenediazonium salts - hydrogenation - vinylphosphonates - Wadsworth-Emmons reactives