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Synlett 2001; 2001(1): 0093-0095
DOI: 10.1055/s-2001-9701
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Asymmetric Dihydroxylations using Immobilized Alkaloids with an Anthraquinone Core

Carsten Bolm* , Astrid Maischak
  • *Institut für Organische Chemie der RWTH Aachen, Professor Pirlet-Str. 1, 52056 Aachen, Germany; Fax +49 241 8888 391; E-mail: Carsten.Bolm@oc.RWTH-Aachen.de
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Publication Date:
31 December 2001 (online)

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In osmium-catalyzed dihydroxylations use of polymer-supported alkaloids with an anthraquinone core allows to obtain optically active diols with high enantioselectivities. Soluble as well as insoluble polymers have been tested for immobilization.

dihydroxylation - asymmetric catalysis - alkaloids - osmium - diols