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Synlett 2022; 33(12): 1137-1141
DOI: 10.1055/a-1709-0280
DOI: 10.1055/a-1709-0280
cluster
Organic Photoredox Catalysis in Synthesis – Honoring Prof. Shunichi Fukuzumi’s 70th Birthday
A Highly Durable, Self-Photosensitized Mononuclear Ruthenium Catalyst for CO2 Reduction
This work was supported by the Asahi Glass Foundation (Step-up-grant to S.S.), the Japan Society for the Promotion of Science (Scientific Research (B) 19H02713 to S.S. and Early-Career Scientists 21K14642 to J. J.), and partially by the Ministry of the Environment of the Government of Japan.
Abstract
A novel mononuclear ruthenium (Ru) complex bearing a PNNP-type tetradentate ligand is introduced here as a self-photosensitized catalyst for the reduction of carbon dioxide (CO2). When the pre-activation of the Ru complex by reaction with a base was carried out, an induction period of catalyst almost disappeared and the catalyst turnover numbers (TONs) over a reaction time of 144 h reached 307 and 489 for carbon monoxide (CO) and for formic acid (HCO2H), respectively. The complex has a long lifespan as a dual photosensitizer and reduction catalyst, due to the sterically bulky and structurally robust (PNNP)Ru framework. Isotope-labeling experiments under 13CO2 atmosphere indicate that CO and HCO2H were both produced from CO2.
Supporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/a-1709-0280.
- Supporting Information
Publikationsverlauf
Eingereicht: 30. August 2021
Angenommen nach Revision: 29. November 2021
Accepted Manuscript online:
29. November 2021
Artikel online veröffentlicht:
05. Januar 2022
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