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Synfacts 2008(12): 1273-1273  
DOI: 10.1055/s-0028-1087309
Synthesis of Materials and Unnatural Products
© Georg Thieme Verlag Stuttgart ˙ New York

Poly(diacetylene)s from Preorganized Monomers

Contributor(s): Timothy M. Swager, Jan M. Schnorr
R. Xu, W. B. Schweizer, H. Frauenrath*
ETH Zürich, Switzerland
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Publikationsdatum:
20. November 2008 (online)

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Significance

The diacetylene 6 containing a phenyl and a perfluorophenyl moiety was synthesized from diyne-diol 2 by reacting first with the phenyl-containing ester 1 and subsequently with the perfluorophenyl-substituted acid chloride 5.