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Synfacts 2009(8): 0887-0887
DOI: 10.1055/s-0029-1217423
DOI: 10.1055/s-0029-1217423
Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
© Georg Thieme Verlag
Stuttgart ˙ New York
Palladium-Catalyzed Asymmetric Dearomatization
J. García-Fortanet, F. Kessler, S. L. Buchwald*
Massachusetts Institute of Technology, Cambridge, USA
Weitere Informationen
Publikationsverlauf
Publikationsdatum:
23. Juli 2009 (online)
Significance
The dearomatization of arenes is recognized as a fundamentally important transformation providing alicyclic frameworks found in many biologically important compounds. The main strategy for the synthesis of these types of compounds requires the use of stoichiometric amounts of metal or reactive reagents, or additional steps to obtain these valuable products.