C-N Bond Formation with Palladium Nanoparticles

L. Adak; K. Chattopadhyay; B. C. Ranu

doi:10.1055/s-0029-1217500

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Synfacts 2009(8): 0937-0937
DOI: 10.1055/s-0029-1217500

Polymer-Supported Synthesis

C-N Bond Formation with Palladium Nanoparticles

Contributor(s): Yasuhiro Uozumi, Norihiro Ishiyama
L. Adak, K. Chattopadhyay, B. C. Ranu*
Indian Association for the Cultivation of Science, Kolkata, India

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Publication History

Publication Date:
23 July 2009 (online)

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Significance

Palladium nanoparticles stabilized by TBAB catalyzed the allylation of various amines 2 with allyl acetates 1 in the presence of K₂CO₃ to give the corresponding N-allylamines 3 in up to 95% yield (25 examples) with high regio- and stereoselectivity.