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Synfacts 2009(11): 1267-1267  
DOI: 10.1055/s-0029-1218038
Metal-Mediated Synthesis
© Georg Thieme Verlag Stuttgart ˙ New York

Co-Catalyzed 1,4-Hydrovinylation

Contributor(s): Paul Knochel, Tobias Thaler
G. Hilt*, M. Danz, J. Treutwein
Philipps-Universität Marburg, Germany
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Publikationsverlauf

Publikationsdatum:
22. Oktober 2009 (online)

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Significance

1-Aryl-substituted 1,3-butadienes and unsymmetrical α,ω-dienes were successfully subjected to a Co-catalyzed 1,4-hydrovinylation reaction. The resulting dienes, trienes or tetraenes are interesting substrates for further transformations and could be used in regioselective alkene metathesis, hydroformylation and hydroboration reactions.