DOI: 10.1055/s-00000131

Synfacts

Issue 11 · Volume 2009 · November 2009 DOI: 10.1055/s-002-20475

Synform

A68
SYNFORM ISSUE 2009/08

Synthesis of Natural Products and Potential Drugs

z1181
All PDFs of this category
1181
Synthesis of (R)-Tolterodine
1182
Synthesis of 4-Hydroxydictyolactone
1183
Synthesis of Kapakahines B and F
1184
Synthesis of Brevenal
1185
Synthesis of Oseltamivir
1186
Synthesis of (-)-Napyradiomycin A1
1187
Synthesis of Fumonisin B1
1188
Synthesis of a Selective PPARγ Modulator
1189
Synthesis of (-)-Corynantheidol
1190
Synthesis of an Oral TACE Inhibitor
1191
Synthesis of Palinurin
1192
Synthesis of (-)-Adaline
1193
Synthesis of (-)-7-Methylomuralide
1194
Synthesis of ()-Hopeanol

Synthesis of Heterocycles

z1195
All PDFs of this category
1195
Mn(III)-Mediated Synthesis of Pyridines
1196
TiCl4-Catalyzed Synthesis of Pyrimido[1,6-a]indol-1-ones
1197
Synthesis of Indoloazocine by Hg(OTf)2-Catalyzed Intramolecular Carbocyclization
1198
Pd-Catalyzed Synthesis of Benzothiophenes from gem-Dihalovinyl Thiophenols
1199
Asymmetric Synthesis of 3-Alkyl-3-aryl-oxindoles
1200
Pd-Catalyzed Synthesis of 3-Bromo-2H-Chromenes
1201
FeCl3-Catalyzed Synthesis of N-Substituted Pyrroles in Water
1202
Rh-Catalyzed Cycloadditions of Unsymmetrical Alkynes with Isocyanates
1203
Synthesis of Tetrahydroisoquinolines and Tetrahydropyridines from Oxaziridines
1204
Cu-Catalyzed Multicomponent Synthesis of 1,2,3,4-Tetrahydropyrimidines
1205
Regioselective One-Pot Straightforward Synthesis of Isoxazoles
1206
Pd-Catalyzed One-Pot Coupling-Annulation Synthesis of Pyrano[4,3-b]quinolines
1207
Au(I)-Catalyzed Synthesis of Cycloalkene-Fused Pyrroles
1208
Synthesis of Fluorinated α-Pyrans
1209
Efficient Cu-Catalyzed Synthesis of 1,2,4-Benzothiadiazine-1,1-dioxides

Synthesis of Materials and Unnatural Products

z1211
All PDFs of this category
1211
Synthesis of Chrysenes through an Unexpected Skeletal Rearrangement
1212
Switchable Molecular Wires
1213
A Molecular Cage with Electrostatic Anchors
1214
Electro-Fluorination of Polymers
1215
Isobenzofurans and Cyclophanes
1216
Regioselective Functionalization of Perylene through C-H Bond Activation
1217
Synthesis and Cyclization of Photochromic Bisarylindenones
1218
High-Yielding Click Route to Macrocycles
1219
Thiophene-Fused Acenes
1220
Symmetric Fullerene Dumbbells
1221
Long Helicenes by Alkyne Cycloisomerization
1222
2-Bromo Benzofurans and Benzothiophenes via Cu-Catalyzed Cross-Coupling
1223
A Platinum Template Strategy to Cyclo[n]thio-phenes
1224
Hooping it up
1225
Catalytic Dicyanation

Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions

z1227
All PDFs of this category
1227
Dibutyltin Dimethoxide and Ag(I)-BINAP-Catalyzed Aldol Reactions of Ketones
1228
Enantioselective Rh-Catalyzed Hydrogena-tion of 3-Aryl-2-phosphonomethylpropenoates
1229
Rhodium-Catalyzed Hydrogenation of β-Keto Enamides
1230
Brønsted Acid Catalyzed Formation of Enynes
1231
Enantioselective Monoallylation of Ammonia
1232
Stereoselective Heck Reaction of Allylic Esters with Arenediazonium Salts
1233
Asymmetric Phase-Transfer Catalytic Alkylation of Imidazoline-4-carboxylates
1234
Copper-Catalyzed Asymmetric Hydroboration of Styrenes
1235
Cu(I)-Catalyzed Asymmetric Conjugate Alkylation with New NHC Ligands
1236
Alkynylation of Acylsilanes via Zinc-Salen Catalysis
1237
Coupling of Imines and Alkynes through Amino Acid and Metal Catalysis
1238
Stereospecific Synthesis of Fluorinated Tetrahydrofurans
1239
pH-Regulated Asymmetric Transfer Hydrogenation of Quinolines in Water
1240
Copper-Catalyzed Allylic Oxidation of 4,5-Epoxycyclohex-1-ene
1241
Chiral Anion-Controlled Axial Chirality of Gold(biphep) Complexes
1242
Copper-Catalyzed Asymmetric Conjugate Boration of Cyclic Enones
1243
Titanium-Catalyzed Thienylation to Ketones
1244
Syntheses of Enantiopure Bicyclic Oxazolidines Using Pd(II) Catalysts
1245
Novel Chiral Mn(II) Complexes for Asymmetric Epoxidation of Olefins
1246
Supramolecular Pd Catalyst for the Reduction of Dihydro-β-Carbolines
1247
Auxiliary-Based Diastereoselective Roskamp Reaction
1248
Direct Aldol Reaction via Dynamic Kinetic Asymmetric Transformation
1249
Zirconocene-Mediated Stereoselective Synthesis of Multisubstituted Vinylsilanes
1250
Dynamic Kinetic Asymmetric Allylation of Hydrazines and Hydroxylamines
1251
Synthesis of γ,δ-Unsaturated Ketones from Methylenecyclopropanes
1252
Rhodium-Catalyzed Formation of syn-α-Allenols
1253
A Modular Approach to the Synthesis of Morpholines
1254
Benzylic Allylation of 2-Substituted Pyridines

Metal-Mediated Synthesis

z1255
All PDFs of this category
1255
Suzuki-Miyaura Coupling through C-CN Bond Cleavage
1256
Direct Metal-Catalyst-Free Reductive Cou-pling of Boronic Acids and Tosylhydrazones
1257
Pd-Catalyzed Direct Alkynylation of C-H Bonds in Benzenes
1258
Direct Arylation of Polyfluoroarenes with Arylboronic Acids
1259
Pd-Catalyzed Synthesis of Isatins from (2-Haloethynyl)nitrobenzenes
1260
Microwave-Assisted Pd-Catalyzed Flavone Synthesis from Arenes
1261
Fe-Catalyzed Oxidative Cyanation of Tertiary Amines
1262
Allylic C-H Amination for the Synthesis of syn-1,3-Amino Alcohols
1263
Au-Catalyzed [3+3] Annulation of Azomethine Imines with Propargyl Esters
1264
Au/Mo-Catalyzed Synthesis of α-Halo-α,β-unsaturated Carbonyls
1265
Pd-Catalyzed Decarboxylative Arylation of C-H Bonds
1266
Direct Synthesis of Phenanthridines via Domino Arylation/N-Arylation
1267
Co-Catalyzed 1,4-Hydrovinylation
1268
Biaryl Cross Coupling Catalyzed by Fe/Co/Ni-Fluorides and NHC Ligands
1269
Zr-Mediated Synthesis of 1,2,4,5-Tetra-substituted Benzenes from Alkynes

Organo- and Biocatalysis

z1271
All PDFs of this category
1271
Lappaconitine Catalysis
1272
Nine-Step Total Synthesis of (+)-Minfiensine
1273
Cascade Reactions Directed by Polarity
1274
Catalytic Wittig Reaction via in situ Phosphine Oxide Recycling
1275
An Effective Combination of Prolinamides and BINOLs
1276
Dienamine Activation in Enantioselective Intramolecular Rauhut-Currier Reactions
1277
anti-Diastereoselective and Enantioselective Hetero-Diels-Alder Reaction
1278
Aminocatalysis Cascades of α-Branched α,β-Unsaturated Aldehydes
1279
Organocatalytic Synthesis of Spiro[pyrrolidin-3,3′-oxindoles]
1280
Secondary Amine/N-Heterocyclic Carbene Catalyzed Cascade Sequence
1281
Guanidinium Salt Catalyzed Imine Hydrophosphonylation
1282
A New Organic Hydrogenation Reagent
1283
Aminocatalysis Cascades of Enones
1284
Hydrogen-Bond-Assisted Hydrogen-Bonding Catalysis
1285
Continuous-Flow Mannich Reactions Using a Solid-Supported Hydroxyproline

Polymer-Supported Synthesis

z1287
All PDFs of this category
1287
Synthesis of Nitriles from Primary Alcohols and NH3 with Ru(OH)x/Al2O3
1288
Aerobic Oxidation of Alcohols with Au/HT
1289
Henry Reaction with Nano-NAP
1290
HClO4-SiO2 Catalyst for Esterification of Carboxylic Acids with Alcohols
1291
Epoxidation of Olefins with Nanoparticle-Supported Mo Complexes
1292
SBNPSA-Catalyzed Formylation and Acetylation of Alcohols and Amines
1293
The Aerobic Oxidation of Benzylic Alcohols with F-MSS Catalyst
1294
Aqueous Suzuki Reactions with PdEDTA in SiO2-Ionic Liquid
1295
SPOS of Natural Products via Ullmann Condensation
1296
Pd/C-Catalyzed N-Debenzylation of Benzylamines
1297
Hexacationic Dendriphos-Pd Complexes for Suzuki-Miyaura Reaction
1298
Asymmetric Alkylation Using Resin-Supported Peptide Catalysts
1299
Aldol Reaction with Polymer-Supported Proline Derivatives
1300
Microwave-Assisted Sonogashira-Type Reaction Using Pd-EnCat

Addenda and Errata

1301
Cyclization/[3+2]-Cycloaddition Reaction of N′-(2-Alkynylbenzylidene) Hydrazides