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Synfacts 2010(3): 0305-0305  
DOI: 10.1055/s-0029-1219270
Synthesis of Materials and Unnatural Products
© Georg Thieme Verlag Stuttgart ˙ New York

N-B Directed Cycloadditions

Contributor(s): Timothy M. Swager, Brett VanVeller
J. F. Vivat, H. Adams, J. P. A. Harrity*
University of Sheffield, UK
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Publikationsdatum:
18. Februar 2010 (online)

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Significance

The authors report a strategy for the synthesis of heteroaromatic borane derivatives using an N-directed cycloaddition reaction. Further, the adducts can be converted into pinicol ­esters or used in direct cross-coupling reactions.