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Synfacts 2010(6): 0707-0707
DOI: 10.1055/s-0029-1219841
DOI: 10.1055/s-0029-1219841
Metal-Mediated Synthesis
© Georg Thieme Verlag
Stuttgart ˙ New York
Direct Amination of Aromatic C-H Bonds Using Oxime Esters
Y. Tan, J. F. Hartwig*
University of Illinois at Urbana-Champaign, USA
Weitere Informationen
Publikationsverlauf
Publikationsdatum:
20. Mai 2010 (online)
Significance
A highly efficient sp² C-H amination using oxime esters is presented. The reaction is proposed to proceed via oxidative addition of the Pd(0) species into the N-O bond. Strong evidence is provided by an isolated Pd(II) complex generated from oxidative addition of Pd(0) into the N-O bond.