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Synfacts 2010(6): 0670-0670
DOI: 10.1055/s-0029-1219903
DOI: 10.1055/s-0029-1219903
Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
© Georg Thieme Verlag
Stuttgart ˙ New York
Ruthenium-Catalyzed Enantioselective Diels-Alder Reaction of β-Keto Esters
C. Schotes, A. Mezzetti*
ETH Zürich, Switzerland
Weitere Informationen
Publikationsverlauf
Publikationsdatum:
20. Mai 2010 (online)
Significance
This is the first enantioselective method for the synthesis of tetrahydro-1-indanones. The product contains an all-carbon quaternary center. The method can be used to synthesize estrone derivatives, which are important for their potential medicinal properties.