RSS-Feed abonnieren
Bitte kopieren Sie die angezeigte URL und fügen sie dann in Ihren RSS-Reader ein.
https://www.thieme-connect.de/rss/thieme/de/10.1055-s-00000131.xml
Synfacts 2010(6): 0667-0667
DOI: 10.1055/s-0029-1219975
DOI: 10.1055/s-0029-1219975
Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
© Georg Thieme Verlag
Stuttgart ˙ New York
New Ligands for Rhodium-Catalyzed Asymmetric 1,4-Additions
F. Lang, D. Li, J. Chen, J. Chen, L. Li, L. Cun, J. Zhu, J. Deng, J. Liao*
Chengdu Institute of Organic Chemistry, Graduate School of Chinese Academy of Science, Beijing and Jiangxi Normal University, Nanchang, P. R. of China
Weitere Informationen
Publikationsverlauf
Publikationsdatum:
20. Mai 2010 (online)
![](https://www.thieme-connect.de/media/synfacts/201006/lookinside/thumbnails/10.1055-s-0029-1219975-1.jpg)
Significance
A new type of tert-butanesulfinylphosphine ligands is successfully synthesized and applied to the rhodium-catalyzed asymmetric 1,4-addition of arylboronic acids to cyclic or acyclic unsaturated ketones. Excellent yield and good enantioselectivity are observed under mild conditions. The stereochemical outcome of this reaction is also discussed.