Photocatalytic Aerobic Oxidation of Alcohols on TiO2

Q. Wang; M. Zhang; C. Chen; W. Ma; J. Zhao

doi:10.1055/s-0030-1259135

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Synfacts 2011(1): 0111-0111
DOI: 10.1055/s-0030-1259135

Polymer-Supported Synthesis

Photocatalytic Aerobic Oxidation of Alcohols on TiO₂

Contributor(s): Yasuhiro Uozumi, Yoichi M. A. Yamada, Maki Minakawa
Q. Wang, M. Zhang, C. Chen, W. Ma, J. Zhao*
Institute of Chemistry, Chinese Academy of Sciences, Beijing and Zhejiang Gongshang University, Hangzhou, P. R. of China

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Publikationsverlauf

Publikationsdatum:
21. Dezember 2010 (online)

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Significance

Photocatalytic aerobic oxidation of alcohols was efficiently performed on H⁺/SiO₂/TiO₂. H⁺/SiO₂/TiO₂ was prepared by treatment of SiO₂/TiO₂ with a Brønsted acid, which exhibited good catalytic performance for the oxidation of alcohols to give the corresponding aldehydes or ketones (5 examples, 85-100% conversion, 87-100% selectivity).