Titanium-Mediated Diastereo- and Enantioselective Dimerization
of Enals

doi:10.1055/s-0030-1260366

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Synfacts 2011(6): 0665-0665
DOI: 10.1055/s-0030-1260366

Metal-Mediated Synthesis

Titanium-Mediated Diastereo- and Enantioselective Dimerization of Enals

Contributor(s): Paul Knochel, Andreas K. Steib
D. T. Cohen, B. Cardinal-David, J. M. Roberts, A. A. Sarjeant, K. A. Scheidt*
Northwestern University, Evanston, USA

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Publication History

Publication Date:
19 May 2011 (online)

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Significance

The paper describes a new N-heterocyclic carbene catalyzed diastereo- and enantioselective dimerization of various enals to yield stereochemically defined cyclic α,β-unsaturated esters.