DOI: 10.1055/s-00000131

Synfacts

Issue 06 · Volume 2011 · June 2011 DOI: 10.1055/s-002-22013

Synform

A46
SYNFORM ISSUE 2011/06

Synthesis of Natural Products and Potential Drugs

z577
All PDFs of this category
0577
Synthesis of NS9544 Acetate
0578
Synthesis of an hNK-1 Receptor Antagonist
0579
Synthesis of the Biaryl Core of Anacetrapib
0580
Synthesis of Kempene-2
0581
Synthesis of ent-Seragakinone A
0582
Synthesis of (±)-Stemoamide
0583
Synthesis of a CXCR3 Antagonist
0584
Synthesis of EBC-23
0585
Synthesis of Efavirenz
0586
Synthesis of AMG 837
0587
n-Nitric Oxide Synthase Inhibitor
0588
Synthesis of Variecolortides A and B
0589
Synthesis of ABT-341
0590
Enantioselective Synthesis of (+)-Salvileucalin B
0591
Syntheses of Guanacastepenes N and O

Synthesis of Heterocycles

z593
All PDFs of this category
0593
Rhodium-Catalyzed Synthesis of Isoquinolines from Oximines and Alkynes
0594
Transition-Metal-Free SNAr-Type Synthesis of Chromones
0595
Synthesis of 1,3-Thiazoles from Nitrostyrenes and Aromatic Thioamides
0596
Palladium-Catalyzed C-H Activation/C-N Coupling Route to 1-Aryl-1H-benzotriazoles
0597
Gold-Catalyzed Hydroamination-Hydroarylation Route to Fused Indoles
0598
Tetrahydropyranoquinolinone via a Knoevenagel Reaction
0599
Synthesis of Quinazolinones by Combined Ullmann Coupling-Oxidative C-H Amidation
0600
One-Pot Synthesis of Indoles and N-Fused Indoles from Nitriles
0601
Nickel-Catalyzed Dehydrogenative [4+2]-Cycloaddition Route to Dihydropyridones
0602
A Catalyst-Free MCR Approach to 1,5-Benzodiazepines
0603
A Boronic Acid Catalyzed Route to Imidazoles. Synthesis of LFA-1 Antagonists
0604
Phenanthridine Synthesis via a Pd-Catalyzed Direct Arylation/N-Arylation Sequence
0605
Zinc(II)-Catalyzed Synthesis of Poly-functionalized Pyrroles
0606
Mn(III)-Catalyzed Synthesis of Pyrroles from Vinyl Azides and β-Keto Acids
0607
Synthesis of Furans via Indium-Catalyzed Rearrangement of Acetylenic Epoxides

Synthesis of Materials and Unnatural Products

z609
All PDFs of this category
0609
Greener 1,1-Difluoroallenes
0610
Bulky, Solid…but still Topochemical!
0611
Porphyrin-Annulene Hybrid
0612
Polyaromatic Furans from Diynyl-1,6-diols
0613
A Concise Route to Functionalized Truxenes
0614
Cyanated Pentacene and Naphthacene as Air-Stable Acene Derivatives
0615
9-H-9-Borafluorene: Hydroboration and Oligomerization
0616
A New Twist to [2.2]Paracyclophanes
0617
The Tale (Tail) of Hemifluorinated Surfactants
0618
Through-Space in a Boat
0619
Red-Shifted Porphyrins
0620
A More Efficient Access to Tetraaza-pentacenes
0621
Octupolar HBC Chromophores

Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions

z623
All PDFs of this category
0623
Catalytic Z-Selective Olefin Cross-Metathesis
0624
Synthesis of 2,3-Disubstituted Indolines by Asymmetric Hydrogenation
0625
Construction of Quaternary Stereogenic Centers from Tertiary Boronic Esters
0626
Catalytic Asymmetric Allylation of Unsaturated Methylidene Ketones
0627
Ruthenium-Catalyzed Asymmetric [2+2] Cycloaddition of Ynamides with Enones
0628
P*,P*-Bidentate Diamidophosphite Ligands in Palladium-Catalyzed Reactions
0629
[3+2] Cycloaddition of Azomethine Ylides and Cyclopropylidene Acetates
0630
Gold-Catalyzed Stereoselective Synthesis of Azetidin-3-ones
0631
Palladium-Catalyzed Enyne Cyclization towards Complex Cyclopentanes
0632
Catalytic Asymmetric Addition of Alkyl Enol Ethers to 1,2-Dicarbonyls
0633
Ligand-Controlled Highly Regioselective and Asymmetric Hydrogenation of Quinoxalines
0634
Vinylogous Mannich Reactions of Fluorinated Aldimines and Siloxyfurans
0635
Diastereo- and Enantioselective Synthesis of Pyrrolidines
0636
Synthesis of Chiral γ-Butyrolactones by a Domino Aldol-Cyclization Reaction
0637
Nickel-Catalyzed Cycloaddition between Phthalic Anhydrides and Allenes
0638
Rh(II)-Catalyzed Stereoselective Cross-Coupling of Diazo Compounds
0639
Asymmetric Synthesis of γ-Butenolides via Sequential Metal-Catalyzed Reactions
0640
Au(I)-Catalyzed Asymmetric Cycloadditions and Mannich Reactions of Azlactones
0641
Asymmetric Addition of Boronic Acids to N-Benzylnicotinate Salts
0642
Copper-Catalyzed Asymmetric Conjugate Addition of Grignard Reagents
0643
Copper-Catalyzed Asymmetric Friedel-Crafts Reaction of Indoles
0644
Ring Opening of Oxabicyclic Alkenes Catalyzed by Multinuclear Complexes
0645
Novel Chiral Diene Ligand for Rhodium-Catalyzed Asymmetric 1,4-Addition
0646
Asymmetric Propargylation of Imines
0647
Combined Rh/Au Catalysis to Form 2,5-Dihydrofurans
0648
Synthesis of γ-Quaternary Acylcyclopentenes via a Ring-Contraction Strategy
0649
Enantio- and Diastereoselective Aldol Reaction of Thioamides
0650
Asymmetric Palladium-Catalyzed Allylic Alkylation of Indoles
0651
Rapid Access to Stereochemically Defined Heterocyclic Scaffolds
0652
Highly Diastereoselective Iron-Mediated C(sp²)-C(sp³) Cross-Couplings

Metal-Mediated Synthesis

z653
All PDFs of this category
0653
Ni-Catalyzed Alkyne Cycloaddition to Give Boronic Esters
0654
Synthesis of Tertiary and Quaternary Allyl- and Crotylsilanes
0655
Synthesis of Polysubstituted Indoles via Three-Component Reaction
0656
Three-Component Cascade Reaction towards Substituted Tetrazoles
0657
C-H Alkylation of Heteroarenes with Alkyl- and Alkoxymethyltrifluoroborates
0658
Cu-Catalyzed Benzylic C-H Oxidation Using Imines as Directing Groups
0659
Cyclobutenone Synthesis from 2,3-Allenoates and Organozincs
0660
A Stereoselective Approach to Tetrasubstituted Silyl Enol Ethers
0661
Cu-Catalyzed Highly Enantioselective 1,4-Addition of Grignard Reagents
0662
Ni-Catalyzed Negishi Cross-Coupling of Secondary Alkylzinc Halides
0663
Base-Mediated Biaryl Formation via Benzyne Intermediates
0664
Pd-Catalyzed Coupling of Tetrafluoroethylene with Arylzinc Compounds
0665
Titanium-Mediated Diastereo- and Enantioselective Dimerization of Enals
0666
Synthesis and Cross-Coupling of Sulfonamidomethyltrifluoroborates
0667
anti-Carbozincation of Diethyl Acetylenedicarboxylate

Organo- and Biocatalysis

z669
All PDFs of this category
0669
Trienamines in Organocatalysis
0670
Metal-Free Aerobic Oxidation of Alcohols
0671
How to Oxidize Methane with a P450 Enzyme
0672
Highly Efficient Hydrogen-Bond Catalysis with (Thio)Phosphorodiamides
0673
Reduction of Quinoxalines: A Convergent Disproportionation Reaction
0674
Catalytic Asymmetric Aminoallylation of Aldehydes
0675
Kinetic Resolution of Allylic Amines via a Dual-Catalysis Approach
0676
Coupled Lewis Base and Phase-Transfer Catalysis for Imine Trifluoromethylation
0677
Z-Selective 1,4-Addition of 5H-Oxazol-4-ones with Alkynyl Carbonyl Compounds
0678
Activation of C(sp³)-H Bond via 1,5-Hydride Transfer-Cyclization
0679
Biocatalytic, Decarboxylative Addition of Malonates to Imines, a ”Rodionovase"
0680
Asymmetric Vinylogous Michael Addition of Furanones to Nitroolefines
0681
Catalytic Asymmetric Chlorocyclization of Unsaturated Amides to Heterocycles

Polymer-Supported Synthesis

z683
All PDFs of this category
0683
Hydrogenation with Iron Nanoparticles Supported on CDG
0684
Suzuki-Miyaura Coupling with Pd(OAc)2 Supported on an Ionic Copolymer
0685
Crotylation and Homopropargylation by Flow Technology
0686
CuFe2O4 Nanoparticles for N-Arylation of Heterocycles
0687
Immobilized DMAP Derivatives Rivaling Homogeneous DMAP
0688
Recyclable Polystyrene-Supported (Dichloroiodo)benzene
0689
Synthesis of N,N-Bicyclic Pyrazolidinones Using Cu(OH)x/Al2O3
0690
Reduction of Nitroarenes and Alkenes with Rh-Fe3O4 Nanocrystals
0691
Suzuki-Miyaura Coupling with Sulfur-Modified Gold-Supported Palladium
0692
Solid-Phase Synthesis of Polyamidoamines
0693
Ring-Closing Metathesis for the Preparation of Cyclic Peptoids
0694
Deoxygenation of Epoxides to Alkenes with H2 Using Au/HT