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Synfacts 2011(6): 0683-0683
DOI: 10.1055/s-0030-1260383
DOI: 10.1055/s-0030-1260383
Polymer-Supported Synthesis
© Georg Thieme Verlag
Stuttgart ˙ New York
Hydrogenation with Iron Nanoparticles Supported on CDG
M. Stein, J. Wieland, P. Steurer, F. Tölle, R. Mülhaupt*, B. Breit*
Albert-Ludwigs-Universität Freiburg and Freiburg Institute for Advanced Studies, Germany
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Publikationsverlauf
Publikationsdatum:
19. Mai 2011 (online)

Significance
Iron nanoparticles supported on chemically-derived graphene (Fe-NP/CDG) were prepared by mixing Fe(CO)5 and chemically-derived graphene (CDG) in the presence of diphenylmethane under sonication conditions (eq. 1). Fe-NP/CDG catalyzed the hydrogenation of alkenes 1 or alkynes 2 to give the corresponding alkanes 3 in up to 100% yield (15 examples, eq. 2).