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Synfacts 2011(6): 0628-0628  
DOI: 10.1055/s-0030-1260434
Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
© Georg Thieme Verlag Stuttgart ˙ New York

P*,P*-Bidentate Diamidophosphite Ligands in Palladium-Catalyzed Reactions

Contributor(s): Hisashi Yamamoto, Kimberly Griffin
K. N. Gavrilov*, S. V. Zheglov, A. A. Shiryaev, N. N. Groshkin, E. A. Rastorguev, E. B. Benetskiy, V. A. Davankov
Ryazan State University and Russian Academy of Sciences, Moscow, Russia
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Publikationsdatum:
19. Mai 2011 (online)

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Significance

Two diamidophospite ligands were used in palladium-catalyzed allylic sulfonylation, alkylation, amination, etherification, and desymmetrization reactions. The novel ligands take ­advantage of the chirogenic phosphorus donor atoms, which create a more efficient chiral environ­ment around the metal.