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Synfacts 2011(6): 0616-0616  
DOI: 10.1055/s-0030-1260403
Synthesis of Materials and Unnatural Products
© Georg Thieme Verlag Stuttgart ˙ New York

A New Twist to [2.2]Paracyclophanes

Contributor(s): Timothy M. Swager, Shuang Liu
X. Liu, Y. Ma*, W. Duan, F. He, L. Zhao, C. Song
Shandong University, Jinan, P. R. of China
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Publikationsdatum:
19. Mai 2011 (online)

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Significance

A series of asymmetrical [2.2]paracyclophane-based macrocycles have been synthesized with the key step being the condensation of diamino[2.2]paracyclophanes and glyoxal. The absolute configurations of the resulting helicenes have been determined by X-ray crystallography and circular dichroism spectroscopy.