Ring Opening of Oxabicyclic Alkenes Catalyzed by Multinuclear
Complexes

doi:10.1055/s-0030-1260437

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Synfacts 2011(6): 0644-0644
DOI: 10.1055/s-0030-1260437

Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions

Ring Opening of Oxabicyclic Alkenes Catalyzed by Multinuclear Complexes

Contributor(s): Hisashi Yamamoto, Zhi Li
K. Endo*, K. Tanaka, M. Ogawa, T. Shibata*
Waseda Institute for Advanced Study, Tokyo and Waseda University, Tokyo, Japan

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Publication History

Publication Date:
19 May 2011 (online)

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Significance

This paper describes a new way to accomplish the asymmetric ring opening of oxabicyclic alkene compounds with dialkyl zinc. Multinuclear Pd/Zn complexes using a BINOL derivative as ligands were proposed to be the effective catalyst. This procedure features simple ligand synthesis, high efficiency, and enantioselectivity.