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Synfacts 2006(3): 0297-0297  
DOI: 10.1055/s-2006-932001
Polymer-Supported Synthesis
© Georg Thieme Verlag Stuttgart · New York

Hydrogenation Reactions Utilizing Capillary Column Reactors

Contributor(s): Yasuhiro Uozumi, Tomohiko Beppu
J. Kobayashi, Y. Mori, S. Kobayashi*
The University of Tokyo, Japan
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Publikationsverlauf

Publikationsdatum:
21. Februar 2006 (online)

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Significance

A less-space and low-cost capillary reactor was developed. Tetrakis(triphenylphosphine)palladium was immobilized onto the inner surface of the capillary column by using the polymer micelle incarceration method. The palladium-immobilized capillary was connected to a T-shaped connector, and hydrogen and a substrate were fed via the connector. Hydrogenation of 1-phenyl-1-cyclohexene gave phenylcyclohexane in a quantitative yield (2.8 mmol/h). No leaching of palladium was observed by ICP analysis after the reactions.