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Synfacts 2006(6): 0531-0531  
DOI: 10.1055/s-2006-934485
Synthesis of Natural Products and Potential Drugs
© Georg Thieme Verlag Stuttgart · New York

Synthesis of Palominol and Dolabellatrienone

Contributor(s): Philip Kocienski, Fiona Black
S. A. Snyder, E. J. Corey*
Harvard University, Cambridge, USA
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Publication History

Publication Date:
19 May 2006 (online)

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Significance

The common central bicyclic core is synthesized using a chiral oxazaborolidinium ion catalyzed enantioselective Diels-Alder reaction and subsequent ring contraction effected by a Wolff rearrangement.