RSS-Feed abonnieren
Bitte kopieren Sie die angezeigte URL und fügen sie dann in Ihren RSS-Reader ein.
https://www.thieme-connect.de/rss/thieme/de/10.1055-s-00000131.xml
Synfacts 2006(9): 0925-0925
DOI: 10.1055/s-2006-949246
DOI: 10.1055/s-2006-949246
Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
© Georg Thieme Verlag Stuttgart · New York
Regiochemical Controlled Transposition of Allylic Silyl Ethers
E. C. Hansen, D. Lee*
University of Wisconsin, Madison, USA
Weitere Informationen
Publikationsverlauf
Publikationsdatum:
23. August 2006 (online)
![](https://www.thieme-connect.de/media/synfacts/200609/lookinside/thumbnails/10.1055-s-2006-949246-1.jpg)
Significance
Stereoselective [1,3]-transposition represents one of the most important synthetic transformations. Regio- and stereoselectivity as well as equilibrium issues always accompany this reaction and prevent efficient generation of the desired rearranged alcohol. This simple two-step protocol offers a powerful alternative to reach higher regioselectivity.