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Synfacts 2007(11): 1172-1172  
DOI: 10.1055/s-2007-991257
Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
© Georg Thieme Verlag Stuttgart · New York

Enantioselective Synthesis of 1,2-Nitro Alcohols

Contributor(s): Mark Lautens, Frédéric Ménard
T. Arai*, M. Watanabe, A. Yanagisawa
Chiba University, Japan
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Publikationsverlauf

Publikationsdatum:
23. Oktober 2007 (online)

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Significance

The present catalytic system is the simplest reported so far for the Henry reaction. The key is the design of a non-C 2 symmetrical ligand L1. The conditions are convenient and the catalyst tolerated air and moisture (copper hydrate salts can be used).