Synfacts

Issue 11 · November 2007

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SYNFORM ISSUE 2007/06 FREE ACCESS

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Synthesis of Natural Products and Potential Drugs
1115
Synthesis of (+)-Asperazine

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1116
Synthesis of Erypoegin H

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1117
Synthesis of (+)-Azaspiracid-1 FREE ACCESS

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1118
Synthesis of (+)-Microcladallene

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1119
Synthesis of (S)-(-)-N-Acetylcolchinol

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1120
Synthesis of (-)-Spongidepsin

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1121
Synthesis of Uncialamycin

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1122
Synthesis of Chlorofusin

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1123
Synthesis of (±)-Dibromophakellstatin

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1124
Synthesis of (+)-Spirolaxine Methyl Ether

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1125
Synthesis of Cruentaren A

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1126
Synthesis of Psymberin

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1127
Total Synthesis of Biyouyanagin A

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1128
Synthesis of (-)-Oseltamivir

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1129
Synthesis of (-)-Oseltamivir

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Synthesis of Heterocycles
1131
Preparation of Perfluoroalkylated 1,2-Dihydropyrimidines and Pyrimidines

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1132
Organocatalytic Domino Michael-Aldol Reaction to Chiral Benzothiopyrans

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1133
Regioselective Synthesis of Pyrazoles from β-Oxo Thioxoesters and α-Oxoketene O,N-Acetals

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1134
Synthesis of Quinolines by Catalyzed Cyclodehydration of Aminoaryl-2-yn-1-ols

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1135
Reductive Cyclization of o-Nitrophenylazophenols to Benzotriazoles

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1136
Asymmetric Synthesis of Chiral Piperazines

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1137
Synthesis of 2,3-Fused Indoles

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1138
Synthetic Routes to 4-Amino-Pyrazoles from Vinamidinium Salts

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1139
Palladium-Catalyzed Hydroamination Route to 2-Substituted Tetrahydroquinolines

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1140
Pyridine Derivatives from Vinylic Phosphazenes via an aza-Wittig Reaction

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1141
Cycloisomerization of Alkynyl Ketones to Multisubstituted Furans

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1142
One-Pot Three-Component Synthesis of Triazoles in Water

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1143
Synthesis of Indoles and Indolines from α-Phosphoryloxy Enecarbamates

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1144
(Pd/C/K-10)-Catalyzed One-Pot Synthesis of Substituted Pyrazoles

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1145
Synthesis of Fused Coumarins via Cycloaddition Reactions

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Synthesis of Materials and Unnatural Products
1147
Low-Temperature Discotic Nematic Liquid Crystals FREE ACCESS

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1148
Conjugated Polymers Bearing Unusual 10 Aromatics

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1149
Cationic Pseudopolyrotaxanes with Cyclodextrins and Cucurbit[6]urils

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1150
Two Polymers from One Monomer

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1151
A Teflon-Footed Resorcinarene

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1152
Spin Trap Radical Detector

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1153
A Reversible Cross-Linker

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1154
Chain-Growth Polymerization to Form Conjugated Polymers

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1155
Shape-Persistent 2D Oligomers

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1156
Coupling Along the Bay

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1157
Nitrogen-Rich Acenes

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1158
Palladium-Catalyzed Synthesis of Rotaxanes

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1159
A Ferrocene-Containing Conjugated Polymer

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Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
1161
Asymmetric Rhodium-Catalyzed [4+3] Cycloaddition FREE ACCESS

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1162
Copper-Catalyzed Conjugate Addition to 2- or 3-Substituted Cylcopent-2-en-1-ones

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1163
Enantioselective Nickel-Catalyzed Aldehyde-Alkyne Coupling

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1164
Iridium-Catalyzed Intermolecular Enantioselective Allylic Amidation

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1165
Fam-Ti-Catalyzed Enantioselective Alkynylation of Aldehydes

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1166
Gold-Catalyzed Addition of Aldehydes to 1,6-Enynes

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1167
Enantioselective and Regiodivergent Nitroso Diels-Alder Reactions

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1168
Barium-Catalyzed Mannich Reaction-Isomerization Sequence

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1169
Palladium-Catalyzed Enantioselective Synthesis of 4-Aryl-4H-chromenes

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1170
Enantioselective Synthesis of 1,1-Disubstituted Propynes

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1171
Enantio- and Diastereoselective Carbonyl Addition of Propargylsilanes

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1172
Enantioselective Synthesis of 1,2-Nitro Alcohols

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1173
Stereoselective Synthesis of Substituted Isoxazolidines

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1174
Tandem Catalysis: Sequential Hydroformylation-Aldol Reactions

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1175
Mannich-Type Reactions Catalyzed by Air-Stable Hf-BINOL Complex

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1176
Diastereoselective Conjugate Addition of Organoboron Nucleophiles

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1177
Asymmetric Nickel-Catalyzed Fluorination of Aryl Acetic Acid Derivatives

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1178
Ammonium Bromides/KF Catalyzed Trifluoromethylation of Carbonyls

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1179
Asymmetric Hydroboration and Diastereoselective Cationic Cyclization

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1180
Domino Hydroformylation/Organocatalytic Aldol Reaction

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1181
Enantioselective Rhodium-Catalyzed Synthesis of N-Arylsuccinimides

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1182
Gold-Catalyzed Synthesis of Cyclohexenediol Derivatives

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1183
Conjugate Addition of Organometallic Reagents to Acyclic Dienones

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1184
α-Substituted Allylboronates: One-Pot Addition to Aldehydes

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1185
Reduction of Vinyl Phenyl Sulfones with Bisphosphine Monoxide Ligands

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1186
Asymmetric [3+3] Cycloaddition of Trimethylenemethane with Nitrones

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1187
Enantioselective Allylation of Imines Directed by Imidazoles

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1188
Enantioselective Synthesis of α-Chiral Aminooxazoles

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Metal-Mediated Synthesis
1189
One-Pot Amidation of Olefins

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1190
Pd/C-Catalyzed Transfer Hydrogenation with Et₃SiH

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1191
Synthesis of Acetophenones via Regioselective Arylation of Vinyl Ethers FREE ACCESS

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1192
Intramolecular Aziridination of Unsaturated N-Tosyloxycarbamates

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1193
Synthesis of Olefins by Cross-Coupling of N-Tosylhydrazones with Aryl Halides

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1194
Palladium-Catalyzed Borylation and Homocoupling of Aryl Chlorides

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1195
First Catalytic Synthetic Application of Indium(I): Allylboration of Ketones

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1196
Regioselective Addition of Aldehydes to Enones Catalyzed by a Ruthenium Hydride Complex

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1197
Iron-Catalyzed Cross-Coupling Reaction Between Alkenyl Grignard Reagents and Alkyl Halides

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1198
Isopropoxide Protection of Aryl Boronates in the Metal-Halogen Exchange

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1199
Selective Iron-Catalyzed Biaryl Coupling: Suppression of Homocoupling

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1200
In(OTf)₃-Promoted Addition of Diethyl Acetamidomalonate to Terminal Alkynes

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1201
Copper-Catalyzed Arylation of Imidazoles and Benzimidazoles

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1202
Suzuki Cross-Coupling Reaction Between Unactivated Alkyl Halides and Alkyl Borates

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Organo- and Biocatalysis
1203
Arylpropionic Alcohols via Enzyme-Mediated Dynamic Kinetic Resolution FREE ACCESS

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1204
Enantioselective 1,3-Dipolar Cycloaddition of Enones and Azomethine Imines

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1205
Organocatalytic Enantioselective Protonation of Silyl Enolates

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1206
Enantioselective 1,4-Addition Reactions of Malonic Acid Half-Thioesters to Nitroolefins

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1207
Enantioselective Conjugate Addition of Aldehydes to Vinyl Phosphonates

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1208
Catalytic Asymmetric Pictet-Spengler Reaction via Sulfenyliminium Ions

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1209
Aerobic Oxidation of Alcohols Using TEMPO@SBA-15

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1210
Enantioselective [3+2] Cycloadditions

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Polymer-Supported Synthesis
1211
Silicium-Supported Metathesis Catalysts

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1212
Vacuum-Driven Anionic Ligand Exchange in a Ruthenium Complex

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1213
α-Oxidation of Ketones Catalyzed by IL-Supported Aryl Iodides

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1214
Phosphinated Polymer-Incarcerated Palladium Catalysts

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1215
Nano-Pd-Catalyzed α-Alkylation of Ketones with Alkanols

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1216
Sulfate Zirconia for Mannich Reaction

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1217
Fe₃O₄ Nanoparticle Supported Crown Ethers

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1218
Suzuki Cross-Coupling Reaction with Chitosan-Supported Palladium(0) Catalyst in Water

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1219
SA-Supported Organic Amines as Heterogeneous Catalysts

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1220
Self-Activating Click Reaction of Peptides

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1221
MeOPEG-Supported Carbene Catalysts

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1222
N-Arylation of Heterocycles Using Nanocrystalline Copper(II) Oxide

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