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Synfacts 2007(11): 1189-1189  
DOI: 10.1055/s-2007-991228
Metal-Mediated Synthesis
© Georg Thieme Verlag Stuttgart · New York

One-Pot Amidation of Olefins

Contributor(s): Paul Knochel, Tobias Thaler
Y. Yasui, S. Tsuchida, H. Miyabe, Y. Takemoto*
Kyoto University, Japan
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Publication History

Publication Date:
23 October 2007 (online)

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Significance

Sequential olefin hydroboration and Pd-catalyzed amidation with carbamoyl chlorides furnishes diverse carbamates in good to excellent yields. Functional groups, such as ester or sensitive silyl groups, are tolerated.