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Synfacts 2008(7): 0699-0699
DOI: 10.1055/s-2008-1077810
DOI: 10.1055/s-2008-1077810
Synthesis of Materials and Unnatural Products
© Georg Thieme Verlag Stuttgart · New York
Rosy Fluorophores
L. Wu, K. Burgess*
Texas A & M University, College Station, USA
Weitere Informationen
Publikationsverlauf
Publikationsdatum:
20. Juni 2008 (online)
Significance
The rosamine derivatives 2a-c were prepared in good to moderate yields from ketone 1. The thioether analogue 2c has a higher fluorescence quantum yield, along with significantly red-shifted absorbance and emission spectra compared to the amino analogues. Secondary amine analogues (not shown) display comparable quantum yields to 2c, but their absorbance and emission spectra are blue-shifted relative to 2a and 2b.