Synfacts

Issue 07 · July 2008

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A61
SYNFORM ISSUE 2008/06 FREE ACCESS

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Synthesis of Natural Products and Potential Drugs
0665
Synthesis of (-)-Kaitocephalin

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0666
Synthesis of (±)-Stemonamide

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0667
Synthesis of (+)-Vigulariol FREE ACCESS

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0668
Synthesis of (+)-WIN 64821 and (-)-Ditryptophenaline

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0669
Synthesis of FK228

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0670
Synthesis of 11-Acetoxy-4-deoxyasbestinin D

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0671
Synthesis of (+)-Phorboxazole A

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0672
Synthesis of (+)-Achalensolide

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0673
Synthesis of (+)-Exiguolide

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0674
Formal Synthesis of (+)-Ottelione A

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0675
Synthesis of (+)-Paeonilactone B

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0676
Synthesis of Mycestericin A

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0677
Synthesis of Neopeltolide

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0678
Synthesis of (+)-Phakellin

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0679
Synthesis of (±)-Fortucine

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Synthesis of Heterocycles
0681
Synthesis of Lactams and Diazepanones via Beckmann Rearrangement

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0682
Synthesis of 4-Iodopiperidines via Aza-Prins Cyclization

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0683
Ireland-Claisen Rearrangement - Michael Addition Sequence to δ-Amino Acids

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0684
Copper-Catalyzed Domino Annulation Reaction to Benzoxazoles

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0685
Iodocyclization-Cross-Coupling Route to Trisubstituted 3-Fluorofurans

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0686
Synthesis of Indolines via C-H Activation of N-tert-Butyl-2-bromoanilines

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0687
Huisgen [2+3]-Cycloaddition Route to Triazolopyrazinones

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0688
ortho Amination of Naphthols by N-N Bond Cleavage of Hydrazines

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0689
Synthesis of Benzofurans via Aryne-Iodonium Ylide Cycloaddition

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0690
Synthesis of Thioindoles Using an Intramolecular Friedel-Crafts Reaction

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0691
Synthesis of Cyclic Sulfamates by a Cascade Process FREE ACCESS

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0692
Synthesis of Indolo[3,2-a]carbazoles by Reaction of Indoles with 1,2-Diones

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0693
Synthesis of Tetrahydroquinolines via CAN-Catalyzed Povarov Reaction

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0694
Organocatalytic Michael Addition of Indoles to Activated Alkenes in Water

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0695
Substituted 1H-Pyrazoles and Isoxazoles from Cyclopropyl Oximes

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Synthesis of Materials and Unnatural Products
0697
Debromination and Ferroelectric Liquid Crystals

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0698
A Self-Immolative Polymer

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0699
Rosy Fluorophores

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0700
Zipped-up Heterojunctions

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0701
Trehalose-Based Cyclodextrin Analogues

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0702
A Modular Approach to Functionalized Benzosiloles

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0703
‘C₆₀ Lunar Lander’ Constructs Direct Electrons at Electrode Interfaces FREE ACCESS

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0704
And Click, Instant Monomer

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0705
Fullerene Derivatives with Variable Thermal Stability

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0706
Harnessing Osmosis to Produce Mechanical Energy

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0707
Fluorine Coating Stops Binuclear Phthalocyanine Aggregation

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0708
Sulfur-Containing Switchable Fluorophore

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0709
Pillar-Shaped Cavitands

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Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
0711
Domino Asymmetric Michael Addition/Ylide Epoxidation

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0712
Addition-Cyclization Protocol for the Enantioselective Synthesis of Furans

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0713
Pd/La Complex for anti-Selective Catalytic Asymmetric Nitroaldol Reactions FREE ACCESS

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0714
Diastereoselective Preparation of 1,2-anti-Dialkylated Synthons

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0715
Nitroaldol Reaction Catalyzed by a Bisoxazolidine Ligand

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0716
Enantioselective Oxidative Dearomatization of Naphthols with Organoiodine(III)

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0717
Iridium-Catalyzed Friedel-Crafts-Type Allylic Alkylation of Indoles

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0718
Scandium-Catalyzed Enantioselective Addition of α-Cyanoketones to Imines

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0719
Formation of a Chiral Quaternary Centers via Asymmetric Hydrovinylation

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0720
Asymmetric Cyclopropanation with Cobalt-Porphyrin Complex

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0721
Adaptive Supramolecular Ligands in Rhodium-Catalyzed Hydrogenation

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0722
Rhodium-Catalyzed Synthesis of Alkynylphosphine Oxides

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0723
Nickel-Catalyzed Stereoselective Cyclo-isomerization of 1,6-Dienes

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0724
ClickFerrophos Ligand in Asymmetric 1,3-Dipolar Cycloaddition

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0725
Tandem Enantioselective Conjugate Addition-Mannich Reactions

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0726
Silver Catalyzed O-Nitroso Aldol Reaction of Silyl Enol Ethers

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0727
Copper(II)-Catalyzed Asymmetric Desymmetrization of Aminoalcohols

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0728
Salen-Chromium Complex Catalyzed Ring Opening of meso-Epoxides

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0729
Enantioselective Conjugate Addition to Nitroalkenes and Nitroacrylates

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0730
Synthesis of Proline Derivatives and α-Aryl Aminoesters via N-H Insertion

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0731
Enantioselective Synthesis of Quaternary l-Valine Derivatives

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0732
Synthesis of Chiral δ-Lactones via a Catalytic Hetero-Diels-Alder Reaction

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0733
Asymmetric Iridium-Catalyzed Hydrogenation of Vinyl Ether Esters and Alcohols

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0734
Synthesis of 1,5-Hexadienes via a Retro-Allylation/Allylation Protocol

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0735
Antimony-Catalyzed Synthesis of Indanones in One Pot

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0736
Enantioselective Propargylic Substitution of Propargylic Acetates with Amines

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0737
Chiral Dinuclear Vanadium Complexes Catalyzed Oxidative Coupling of 2-Naphthols

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0738
Domino Stereoselective Cross-Metathesis-Imine Cinnamylation

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0739
Rhodium-Catalyzed Enantioselective Silaboration of α,β-Unsaturated Esters

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Metal-Mediated Synthesis
0741
Suzuki-Miyaura Cross-Coupling of Trifluoroboratohomoenolates FREE ACCESS

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0742
Selective Formation of Acetals and Ketals, Catalyzed by Indium(III) Triflate

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0743
Biaryls via a One-Pot Borylation-Cross-Coupling Sequence Using Pinacolborane

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0744
Palladium-Catalyzed Cross-Coupling Reactions with Tricyclopropylbismuth

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0745
FeCl₂-Catalyzed Amidation of C-H Bonds with N-Bromosuccinimide as Oxidizing Agent

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0746
Isoquinolone Synthesis via Decarbonylative Addition of Phthalimides to Alkynes

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0747
Rhodium(I)-Catalyzed Hydration of Organonitriles

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0748
Palladium-Catalyzed Cleavage of C-C Triple Bonds with Molecular Oxygen

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0749
Copper(II)-Mediated N-Cyclopropylation of Indoles and Cyclic Amides

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0750
Palladium-Catalyzed α-Arylation of Esters

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0751
Synthesis of Enones via Nickel-Catalyzed Carbonylative Negishi Cross-Coupling

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0752
Mo-Au Combo Catalysis in 1,3-Rearrange-ment of Propargyl Alcohols

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0753
MeReO₃-Catalyzed Selective Oxidation of Thiols to Sulfonic Acids

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0754
Vinylation and Difluorovinylation of Arylboronic Acids with Vinyl Tosylates

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Organo- and Biocatalysis
0755
A New Phosphinothiourea Catalyst

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0756
Brønsted Acid Catalyzed Vinylogous Mannich Reaction

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0757
Organocatalytic Approach to α-Substituted syn-α,β-Diamino Acids

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0758
Combined Organo- and Transition-Metal Catalysis Cascade to Cyclopentenes

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0759
Asymmetric Transfer Hydrogenation in Aqueous Media

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0760
High-Throughput Screening for a Biocatalytic Asymmetric Ketone Reduction

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0761
Methyl Cation Affinities of Organocatalysts

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0762
Synthesis of Tetrahydropyrans via a Domino Aldol-Acetalization Reaction

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0763
Organocatalytic Ring-Opening Reactions in a Molecular Vessel

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0764
Formation of Piperidines by Asymmetric Formal Aza-[3+3] Cycloaddition

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0765
Aldehyde Activation by Binol-Derived Phosphoric Acids

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Polymer-Supported Synthesis
0767
Selective Reduction of the Nitro Group Using Nanocyrstalline MgO-Stabilized Palladium(0)

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0768
Synthesis of Propargylamines Catalyzed by Nanocrystalline Copper(II) Oxide

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0769
Microwave-Assisted Ring-Opening of Aziridines Using Resin-Bound Amines

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0770
Polymer-Supported Gadolinium Triflate as a Lewis Acid Catalyst

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0771
Synthesis of α-Alkylidene Cyclic Carbonates

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0772
Silane Alcoholysis and Silylative Pinacol Coupling with Gold Nanoparticles

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0773
Transfer Hydrogenation of Allylic Alcohols Using Ru(OH)_x/Al₂O₃

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0774
InCl₃/SiO₂-Catalyzed Hydroarylation

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0775
Cross-Coupling of ArN₂BF₄ with ArB(OH)₂

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0776
Hiyama Cross-Coupling Using Palladium Nanoparticles

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0777
A³-Coupling with Silica-Supported Copper Complex

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0778
Heteropoly Acid Catalyzed Hydroamination of Alkenes FREE ACCESS

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0779
Silica-Alumina-Supported Amine Catalysts for C-C Bond Formations FREE ACCESS

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