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Synlett 2021; 32(16): 1633-1636
DOI: 10.1055/a-1457-2399
DOI: 10.1055/a-1457-2399
cluster
Modern Nickel-Catalyzed Reactions
Nickel-Catalyzed Photodehalogenation of Aryl Bromides
We thank Institut Català d’Investigació Química (ICIQ) and the Fondo Europeo de Desarrollo Regional (FEDER/MCI, AEI/PGC2018-096839-B-I00) for financial support. B. H. thanks ‘La Caixa’ Foundation (ID 100010434 and LCF/BQ/DI18/11660031) for a predoctoral fellowship.
Abstract
Herein, we describe a Ni-catalyzed photodehalogenation of aryl bromides under visible-light irradiation that utilizes tetrahydrofuran as hydrogen source. The protocol obviates the need for exogeneous amine reductants or photocatalysts and is characterized by its simplicity and broad scope, including challenging substrate combinations
Supporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/a-1457-2399.
- Supporting Information
Publication History
Received: 23 February 2021
Accepted after revision: 21 March 2021
Accepted Manuscript online:
21 March 2021
Article published online:
14 April 2021
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