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Synfacts 2009(9): 1024-1024
DOI: 10.1055/s-0029-1217696
DOI: 10.1055/s-0029-1217696
Metal-Mediated Synthesis
© Georg Thieme Verlag
Stuttgart ˙ New York
AgOTf-Mediated Fluorination of Boronic Acids
T. Furuya, T. Ritter*
Harvard University, Cambridge, USA
Further Information
Publication History
Publication Date:
21 August 2009 (online)
Significance
The authors report a regiospecific silver-mediated fluorination reaction of aryl- and alkenylboronic acids. It can be conveniently performed on a multigram scale and proceeds without additional ligands. The respective aryl or alkenyl fluorides are obtained in high yields and under tolerance of a variety of functional groups.