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Synfacts 2010(3): 0333-0333  
DOI: 10.1055/s-0029-1219313
Metal-Mediated Synthesis
© Georg Thieme Verlag Stuttgart ˙ New York

Nickel-Catalyzed Suzuki-Miyaura Coupling of Aryl Carbamates, Carbonates, and Sulfamates

Contributor(s): Paul Knochel, Tobias Thaler
K. W. Quasdorf, M. Riener, K. V. Petrova, N. K. Garg*
University of California, Los Angeles, USA
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Publication History

Publication Date:
18 February 2010 (online)

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Significance

Efficient Suzuki-Miyaura cross-coupling of aryl carbamates, carbonates, and sul­famates was implemented. The reaction proceeds with moderate to good yields at elevated temperatures using an air-stable nickel(II) catalyst.