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Synfacts 2010(6): 0658-0658
DOI: 10.1055/s-0029-1219981
DOI: 10.1055/s-0029-1219981
Synthesis of Materials and Unnatural Products
© Georg Thieme Verlag
Stuttgart ˙ New York
Boron Group Transfer Polymerization
K. Uehara, C. B. Wagner, T. Vogler, H. Luftmann, A. Studer*
Westfälische Wilhelms-Universität Münster, Germany
Further Information
Publication History
Publication Date:
20 May 2010 (online)
![](https://www.thieme-connect.de/media/synfacts/201006/lookinside/thumbnails/10.1055-s-0029-1219981-1.jpg)
Significance
The authors report the use of catecholboron enolate 1 as a regulator for radical polymerization of various vinyl ketone derivatives. The regulator brings about highly controlled polymerizations, and the polymers obtained using this method show polydispersity index (PDI) values that are significantly smaller than those obtained in the absence of 1.