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Synfacts 2010(8): 0935-0935
DOI: 10.1055/s-0030-1257763
DOI: 10.1055/s-0030-1257763
Metal-Mediated Synthesis
© Georg Thieme Verlag
Stuttgart ˙ New York
Arylsilane Oxidation - New Routes to Hydroxylated Aromatics
S. Bracegirdle, E. A. Anderson*
University of Oxford, UK
Further Information
Publication History
Publication Date:
22 July 2010 (online)
Significance
An efficient route to functionalized phenol derivatives has been developed via the oxidation of aryl organosilanes with good tolerance towards functional groups. The reaction proceeds under relatively mild conditions using substoichiometric amounts of TBAF.