Chromium-Catalyzed Enantioselective Synthesis of 1,3-Butadien-2-ylcarbinols

M. Durán-Galván; B. T. Connell

doi:10.1055/s-0030-1257825

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Synfacts 2010(8): 0913-0913
DOI: 10.1055/s-0030-1257825

Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions

Chromium-Catalyzed Enantioselective Synthesis of 1,3-Butadien-2-ylcarbinols

Contributor(s): Hisashi Yamamoto, Jiajing Tan
M. Durán-Galván, B. T. Connell*
Texas A&M University, College Station, USA

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Publikationsdatum:
22. Juli 2010 (online)

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Significance

In this paper, a chromium tridentate carbazole complex was demonstrated to be an effective catalyst for the enantioselective allenylation of aromatic or aliphatic aldehydes. Various 1,3-butadien-2-ylcarbinols were obtained with moderate to good yields and enantioselectivities.