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Synfacts 2011(1): 0079-0079
DOI: 10.1055/s-0030-1259116
DOI: 10.1055/s-0030-1259116
Metal-Mediated Synthesis
© Georg Thieme Verlag
Stuttgart ˙ New York
A Selective and General Palladium Catalyst for the Oxidative Heck Reaction
E. W. Werner, M. S. Sigman*
University of Utah, Salt Lake City, USA
Further Information
Publication History
Publication Date:
21 December 2010 (online)
Significance
The authors report a highly selective, general oxidative Heck reaction, proceeding under mild conditions without the need for base or high temperatures. The olefin substrates can be electronically nonbiased and do not require specific directing groups.