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Synlett 2014; 25(16): 2281-2284
DOI: 10.1055/s-0034-1378371
DOI: 10.1055/s-0034-1378371
cluster
Regio- and Diastereoselective Nickel-Catalyzed Cycloaddition of Activated Cyclopropanes with Allenes
Further Information
Publication History
Received: 14 May 2014
Accepted after revision: 11 June 2014
Publication Date:
06 August 2014 (online)
![](https://www.thieme-connect.de/media/synlett/201416/lookinside/thumbnails/10.1055-s-0034-1378371-1.jpg)
Abstract
Nickel-catalyzed intermolecular [3+2] cycloaddition of activated cyclopropanes with allenes has been developed. This transformation generates highly substituted five-membered carbocyclic compounds with good regio- and diastereoselectivity under mild reaction conditions. This reaction can be extended to a broad variety of allenes to obtain the corresponding adducts.
Supporting Information
- for this article is available online at http://www.thieme-connect.com/products/ejournals/journal/ 10.1055/s-00000083.
- Supporting Information
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For reviews, see:
Methylene cyclopropanes:
Cyclopropyl ketones:
Vinylcyclopropanes:
Cyclopropenones: