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Synfacts 2019; 15(10): 1133
DOI: 10.1055/s-0039-1690666
DOI: 10.1055/s-0039-1690666
Metals in Synthesis
Regio- and Enantioselective Cobalt-Catalyzed Allylic Amination
Further Information
Publication History
Publication Date:
17 September 2019 (online)
Significance
The authors report an enantioselective cobalt-catalyzed allylic amination of racemic allylic carbonates that leads to highly branched products.
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Comment
A broad range of aliphatic and aromatic amines are used, providing a variety of amines in excellent yields and enantioselectivities.
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