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Synfacts 2022; 18(06): 0653
DOI: 10.1055/s-0041-1737468
Polymer-Supported Synthesis

Acceptorless Alcohol Dehydrogenation with an Iron–Cobalt Double-Atom Catalyst

Contributor(s):
Yasuhiro Uozumi
,
Aya Tazawa
Liu C, Li T, Dai X, Zhao J, He D, Li G, Wang B, Cui X. * Lanzhou Institute of Chemical Physics, P. R. of China
Catalytic Activity Enhancement on Alcohol Dehydrogenation via Directing Reaction Pathways from Single- to Double-Atom Catalysis.

J. Am. Chem. Soc. 2022;
144: 4913-4924
DOI: 10.1021/jacs.1c12705
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Key words

double-atom catalyst - iron catalysis - cobalt catalysis - dehydrogenation - alcohols

Significance

An Fe–Co double-atom catalyst supported on N-doped carbon (FeCo-DAC), prepared according to equation 1, catalyzed the dehydrogenation of alcohols to afford the corresponding aldehydes or ketones in ≤98% yield with generation of H2 gas (eqs. 2 and 3).


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Comment

FeCo-DAC was characterized by means of XRD, XPS, Raman, ICP-AES, TEM, HAADF-STEM, EDX, XANES, and EXAFS analyses. In the dehydrogenation of benzyl alcohol, the catalytic activity of FeCo-DAC was superior to that of the corresponding Fe and Co single-atom catalysts or other supported metal catalysts, such as Pd/C or Ru/C.


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Publication History

Article published online:
17 May 2022

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