Porphyrin-Chlorin Dyads by 1,3-Dipolar Cycloaddition

A. M. G. Silva; P. S. S. Lacerda; A. C. Tomé; M. G. P. M. S. Neves; A. M. S. Silva; J. A. S. Cavaleiro; E. A. Makarova; E. A. Lukyanets

doi:10.1055/s-2006-955682

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Synfacts 2007(1): 0040-0040
DOI: 10.1055/s-2006-955682

Synthesis of Materials and Unnatural Products

Porphyrin-Chlorin Dyads by 1,3-Dipolar Cycloaddition

Contributor(s): Timothy M. Swager, Changsik Song
A. M. G. Silva, P. S. S. Lacerda, A. C. Tomé, M. G. P. M. S. Neves, A. M. S. Silva, J. A. S. Cavaleiro*, E. A. Makarova, E. A. Lukyanets
University of Aveiro, Portugal and Organic Intermediates and Dyes Institute, Moscow, Russian Federation

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Publication History

Publication Date:
15 December 2006 (online)

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Significance

Cavaleiro and co-workers constructed porphyrin-chlorin and porphyrin-tetraazachlorin dyads through 1,3-dipolar cycloaddition with azomethine ylide 1 generated in situ. Following the finding that porphyrin can participate in 1,3-dipolar cycloadditions, the authors synthesized porphyrinic azomethine ylide 1, which can react with various dipolarophiles including several porphyrines.