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Synfacts 2008(5): 0500-0500
DOI: 10.1055/s-2008-1072667
DOI: 10.1055/s-2008-1072667
Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
© Georg Thieme Verlag Stuttgart · New York
Iridium-Catalyzed Asymmetric Allylic Etherification
S. Ueno, J. F. Hartwig*
University of Illinois Urbana-Champaign, USA
Weitere Informationen
Publikationsverlauf
Publikationsdatum:
23. April 2008 (online)
Significance
The iridium-catalyzed enantioselective allylic etherification with aliphatic alcohols and silanols is reported. The corresponding allylic ethers are obtained in good yields and excellent enantio- and regioselectivities. This method is general and versatile for aliphatic alcohols, including tertiary alcohols.