DOI: 10.1055/s-00000131

Synfacts

Issue 05 · Volume 2008 · May 2008 DOI: 10.1055/s-002-12521

Synform

A49
SYNFORM ISSUE 2008/05

Synthesis of Natural Products and Potential Drugs

0441
Synthesis of Thromboxane B2
0442
Synthesis of (+)-Didemniserinolipid B
0443
Synthesis of (-)-Pseudolaric Acid B
0444
Synthesis of (+)-Sch 642305
0445
Synthesis of Norbadione A
0446
Synthesis of Pasteurestin A and B
0447
Synthesis of (-)-Okilactomycin
0448
Synthesis of (+)-Upial
0449
Synthesis of (-)-Pentalenene
0450
Synthesis of (-)-Hennoxazole A
0451
Synthesis of Shimalactone A
0452
Synthesis of Three Lycopodium Alkaloids
0453
Total Synthesis of (+)-Neopeltolide
0454
Synthesis of (±)-Psychotrimine
0455
Synthesis of Palmitoyl Caprazol

Synthesis of Heterocycles

0457
Pyrazolidinones via Amination of Homoenolates Catalyzed by N-Heterocyclic Carbenes
0458
Electrochemical Cyclization of 2-Alkynylanilines to Indole Derivatives
0459
Palladium-Catalyzed Carbonylative 3-Component Synthesis of Quinazolinones
0460
Silver-Catalyzed Synthesis of Spiroisoindole-butyrolactones
0461
Iron-Catalyzed Friedel-Crafts Synthesis of Dihydro- and Tetrahydroisoquinolines
0462
Palladium-Catalyzed Three-Component Synthesis of Phenothiazines
0463
Aziridines in Heteroannulation. Synthesis of 1,4-Benzodiazepines
0464
Diastereoselective Synthesis of Nitropiperidones from N-p-Tolylsulfinyl β-Nitroamines
0465
Synthesis of Fluorinated Heteroaromatics by [3+2] Cycloaddition of N-Oxides with Hexafluoropropene
0466
Synthesis of Fluorinated Quinolines and a Pyrazoloquinoline
0467
Synthesis of 4-Hydroxypipecolic Acid β-Lactam Analogues from Oxoazetidines

Synthesis of Materials and Unnatural Products

0469
Donor-Acceptor Complexes with High Quantum Yields and Large Stokes Shifts
0470
A [2+2] Approach to Unsymmetrical Chlorins
0471
Biocompatible Release Valve
0472
A Chiral Metal-Organic Framework
0473
Soluble and Conjugated Poly(2,6-anthrylene)
0474
Double the Photons for Selectivity
0475
C60 Bound to a Shape-Persistent Aryl Amide Macrocycle
0476
Carbon Dioxide Trap-Release Polymers
0477
Well-Defined Liquid Crystal Gels
0478
Acyclic Carbohydrate Receptor
0479
An Organic Spin Cage
0480
A ‘Natural’ Synthesis of Acenequinones
0481
Cooperative Binding by a Bicyclic Calixpyrrole

Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions

0483
Catalytic Reformatsky Reaction
0484
Strontium-Catalyzed Enantioselective Michael Reactions
0485
Rhodium-Catalyzed Enantioselective Hydroacylation of Ketones
0486
Aldol Additions to Aldehydes with an Indathiazolidinethione Auxiliary
0487
Dinuclear Aluminum Salen Displays Expanded Substrate Scope with Conjugate Cyanation
0488
Ni2-Schiff Base Complex for Synthesis of α-Tetrasubstituted α,β-Diamino Acid Precursors
0489
Chiral Bis-Sulfoxide/Rhodium(I) Catalyzed Asymmetric Addition of Arylboronic Acids
0490
Direct Amination via Bifunctional Iridium Amido Complex
0491
Nickel-Catalyzed Cross-Coupling of Benzyl Bromides and Trialkynylindium Reagents
0492
Chiral N,N-Dioxide/Indium(III) Complex Catalyzed Asymmetric Hetero-Diels-Alder Reaction
0493
Enantioselective Allylic Etherification Using Novel Ferrocenyl Ligand
0494
Rhodium(I)-Catalyzed Cycloaddition of 1,6-Enynes and Electron-Deficient Ketones
0495
Zinc-Catalyzed Asymmetric Addition of Allylboronates
0496
Synthesis of Chiral Glutamic Acid By Conjugate Addition
0497
Palladium-Catalyzed Asymmetric Heck Reactions with Aryl and Vinyl Chlorides
0498
Diastereoselective Synthesis of Fluorinated Cyclopentene Derivatives
0499
Cationic Dirhodium Carboxamidates for Lewis Acid Catalyzed Reactions
0500
Iridium-Catalyzed Asymmetric Allylic Etherification
0501
Zinc-Catalyzed Asymmetric Friedel-Crafts Alkylation of Pyrroles
0502
Asymmetric Hydrogenation of Farnesol and O-Protected Derivatives
0503
Ru(II)-Catalyzed Highly Enantioselective Hydrogenation of Acyl Silanes
0504
Stereoselective Synthesis of Highly Substituted Cyclopropanes
0505
Iridium-Promoted C-C Coupling through Transfer Hydrogenation
0506
Oxaziridines as Nitrone Precursors for [2+3] Cycloadditions
0507
Rhodium-Catalyzed Desymmetrization of Diazabicycles with Chemodivergence
0508
Gold- and Palladium-Cocatalyzed Vinylstannylation of Alkynes
0509
Asymmetric Allylic Alkylation with ‘Hard’ Amide Carbanions
0510
Rhodium-Catalyzed Stereoselective Synthesis of Nitrile-Substituted Cyclopropanes
0511
Solvent-Dependent Chemodivergent Synthesis of Cyclic Ethers
0512
Rhodium-Catalyzed Conjugate Addition of Sterically Bulky Silylacetylene to Enones

Metal-Mediated Synthesis

0513
One-Pot Sonogashira and Decarboxylative Coupling of sp and sp2 Carbons
0514
Palladium-Catalyzed Arylation of (Het)arenes with Arylboronic Acids
0515
Carbonylation of Aryl Tosylates and Mesylates
0516
Copper-Catalyzed 1,2-Double Amination of 1-Halo-1-alkynes
0517
Indium(I)-Catalyzed Allylation of Acylhydrazones with Pinacolyl Allylboronates
0518
Synthesis of Salt-Free Diorganozinc Reagents and Their Use in Asymmetric Reactions
0519
Palladium-Catalyzed 1,2- and 1,1-Aryl-halogenation of Alkenes
0520
Phosphinamide-Directed Stereoselective Benzylic Lithiation
0521
Copper-Catalyzed Coupling of Hydroxylamines with Aryl Iodides
0522
C-C Bond-Formation Catalyzed by Nickel on Graphite
0523
Synthesis of Oxazolones via Copper(II)- and Gold(I)-Catalyzed Transformations
0524
Silver(I)-Catalyzed Benzylation and Allylation Reactions of Alkyl Halides
0525
Syntheses of Three- and Five-Membered Carbocycles via Diene-Titanium Complexes
0526
Oxygen- and Base-Free Oxidative Coupling of Arylboronic Acids with Olefins

Organo- and Biocatalysis

0527
Vinylogous Umpolung with Nitrosobenzene
0528
Three-Component Cyclization to Dihydropyridines
0529
Desymmetrization of Meso Anhydrides
0530
Asymmetric Morita-Baylis-Hillman Reaction of Aryl Aldehydes
0531
Enantioselective Reduction of N-Arylketimines with S-Chiral Catalysts
0532
Asymmetric Mannich Reaction of Acetaldehyde
0533
Direct Crossed-Aldol Reaction of Acetaldehyde
0534
Kinetic Resolution of Aryl Alkanols by Homobenzotetramisole
0535
Biginelli Reaction via Dual Activation
0536
Brønsted Acid Catalyzed Enantioselective 1,3-Dipolar Cycloaddition
0537
Diels-Alder Reaction of 2-Pyrones and α,β-Unsaturated Ketones

Polymer-Supported Synthesis

0539
Transfer Hydrogenation of Carbonyl Compounds Using Nickel Nanoparticles
0540
Monoesterfication of Alkylphosphonic Acids by DCC-Celite
0541
Suzuki-Miyaura Coupling Reaction Using Palladium Nanoparticles Immobilized on SPB
0542
Asymmetric Alkylation Using Polymer-Supported Cinchona Ammonium Salts
0543
m-Iodosylbenzoic Acid Mediated Iodo-Functionalization
0544
Siloxane-Supported Bisoxazoline Ligands
0545
Polymer-Supported (Salen)Al Catalysts
0546
Hydrothiolation of Alkynes Using a Solid-Supported Catalyst
0547
Aerobic Oxidation of Primary Amines by DPPH-WO3/Al2O3 Catalyst
0548
Asymmetric Michael Additions with Polymer-Supported Pyrrolidine Derivatives
0549
Ring-Opening of Epoxides with Amines by Zn(ClO4)/Al2O3
0550
Heck Reaction with Silica Gel Supported Palladium Nanoparticles