Synfacts

Issue 12 · December 2007

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A73
SYNFORM ISSUE 2007/07 FREE ACCESS

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Synthesis of Natural Products and Potential Drugs
1223
Synthesis of Pyrrole-Based HMG-CoA Reductase Inhibitors

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1224
Synthesis of Herboxidiene/GEX 1A

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1225
Synthesis of Salvinorin A FREE ACCESS

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1226
Synthesis of Pinnaic Acid

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1227
Synthesis of (±)-Terpestacin

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1228
Synthesis of (+)-Isomigrastatin

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1229
Synthesis of Thapsigargin

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1230
Synthesis of (-)-Agelastatin

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1231
Formal Synthesis of (-)-Platensimycin

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1232
Synthesis of Arglabin

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1233
Synthesis of (-)-d-erythro-Sphingosine

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1234
Synthesis of (-)-Archazolid B

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1235
Synthesis of Leucascandrolide A

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1236
Synthesis of (+)-Enshuol

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1237
Synthesis of Methyl Sarcophytoate

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Synthesis of Heterocycles
1239
Copper-Catalyzed α-Enolate Arylation Route to 2,3-Disubstituted Indoles

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1240
Synthesis of Pyrazolidines via GaCl₃-Catalyzed Insertion of Diazines into Cyclopropanes

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1241
Sequential Hydroamination-Fischer Cyclization Route to Indoles

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1242
Stereoselective Ring Contraction of Diketopiperazines into Pyrrolidine-2,4-diones

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1243
Zinc Triflate Catalyzed Synthesis of Condensed Maleimides and Carbazoles

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1244
Palladium-Catalyzed Synthesis of Benzothiazoles Using a Thiol Surrogate

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1245
C-H-Activated ortho-Arylation of Anilides and Their Cyclization to Phenanthridines

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1246
Synthesis of Benzothiazoles and Benzoxazoles from Thiobenzamides

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1247
Copper-Catalyzed Intramolecular Cyclization of 2-Haloacetanilines to Benzo[d]oxazoles

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1248
Regioselective Suzuki Cross-Coupling Route to 3,4-Disubstituted Quinolin-2(1H)-ones

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1249
Copper-Catalyzed Heteroannulation of Propargylic Pyridines to Indolizines

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1250
Synthesis of Substituted Furans via Silica-Supported Silver Catalysis

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1251
Cu-Catalyzed Synthesis of Imidazo[1,2-a]pyridines from α-Diazoketones and 2-Aminopyridines

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1252
AlCl₃-Mediated Synthesis of Furans from Acid Chlorides and bis-Silylated Butadiene

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1253
Three-Component Synthesis of Furylnicotinamides and Isonicotinamides

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Synthesis of Materials and Unnatural Products
1255
Giant Polycyclic Aromatic Hydrocarbons and the Metals That Bind Them

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1256
A Dynamic Covalent Approach FREE ACCESS

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1257
A Self-Threading Needle

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1258
Synthesis of 2,3,6,7-Tetrabromonaphthalene Diimide

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1259
Bright Blue-Emitting Ce³⁺ Complexes

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1260
A Controlling Neighbor

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1261
Reversible Cross-Linking via Covalent Bonds

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1262
Boron-Based Acenes

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1263
Light-Powered Molecular Shuttle

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1264
New Class of Chromophores via Cascade Reactions

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1265
An Iterative Synthesis of π-Conjugated Oligomers

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1266
Unusual Liquid Crystal Organization

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1267
An Anion-Sensing Capsule

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Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
1269
Transannular Diels-Alder Reaction Catalyzed by Chiral Oxazaborolidine FREE ACCESS

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1270
Asymmetric Allylic Amination with Ammonia Equivalents

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1271
Iron-Catalyzed Epoxidations with Hydrogen Peroxide FREE ACCESS

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1272
Highly Active Rhodium-Diene Complexes for [4+2] Cycloadditions

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1273
Phosphine-Directed Diastereoselective Allylic Substitutions

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1274
Synthesis of Chiral β-Branched α-Amino Acids from Glycine

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1275
Intramolecular Pauson-Khand Reactions with Ir(phox) Catalysts

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1276
Silver-Catalyzed Diastereoselective 1,3-Dipolar Cycloadditions

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1277
Asymmetric Hydrogenation of Unprotected α-Amino Ketones

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1278
Asymmetric Reductive Coupling of 1,3-Enynes to Glyoxalates

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1279
Enantioselective Au(I)-Catalyzed Cycloisomerization of Eneallenes

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1280
Rhodium-Catalyzed Reaction of Alkynyl Oxiranes with Arylboronic Acids

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1281
Mechanistic Insight into Iridium-Catalyzed Asymmetric Allylations

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1282
Catalytic Enantioselective Tautomerization of Isolated Enols

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1283
Enantioselective Carbonyl-Ene Reaction with a Modified Salen Catalyst

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1284
Regioselective Synthesis of sec- and tert-Allylamines

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1285
C-S Bond Formation by Iron-Catalyzed Michael Addition of Thiols

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1286
Palladium-Catalyzed Asymmetric Diamination

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1287
Copper-Catalyzed Asymmetric N-H Insertions

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1288
Direct Mannich Reactions: Synthesis of Protected anti-α,β-Diamino Acids

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1289
Enantioselective 1,3-Dipolar Cycloadditions with Silver Catalysts

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1290
Asymmetric 1,2-Addition of Organoalanes to Cyclic Enones

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1291
Quaternary Allylic Amines by Asymmetric Aza-Claisen Rearrangements

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1292
New Ligands for Rhodium-Catalyzed Asymmetric Hydrogenation of Olefins

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1293
Asymmetric Addition of Organoboron to Alkenes by Oxidative Pd(II) Catalysis

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1294
Use of Fluorinated Alcohols in Enantioselective Hydrogenation

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Metal-Mediated Synthesis
1295
Alkynylation of Epoxides with Alkynylalanes at the More Hindered Carbon

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1296
Palladium-Catalyzed Silylation of Aryl Chlorides with Hexamethyldisilane

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1297
Cobalt-Catalyzed Reductive Coupling of Activated Alkenes with Alkynes FREE ACCESS

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1298
Copper-Catalyzed Sulfonylation of Arylboronic Acids

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1299
Aryl Ketones by Palladium-Catalyzed Coupling of Aryl Bromides with Enol Acetates

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1300
Reductive Perfluoroalkylation of Esters with Perfluoroalkyl Titanates

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1301
Rhodium-Catalyzed O-Silylation of Alcohols with Vinyl Silanes

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1302
Selective Preparation and Reactions of Propargylic Grignard Reagents

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1303
Radical Carbohydroxylation of Olefins with Aryl Diazonium Salts and TEMPO

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1304
Copper-Catalyzed α-Arylation of Malonates

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1305
Copper-Catalyzed Amidation with Chloramine T

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1306
Intramolecular Heck Reaction of Unactivated Alkyl Halides

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1307
Efficient Ruthenium-Catalyzed Oxime-to-Amide Rearrangement

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Organo- and Biocatalysis
1309
Chiral Tetraaminophosphonium Salts: A New Catalyst Motif FREE ACCESS

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1310
Direct Oxyamination Reaction of Aldehydes with Nitrosobenzene

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1311
Direct Aldol-Type Reaction of Oxindoles with Ethyl Trifluoropyruvate

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1312
Oxidative Coupling of 3-Substituted Catechols

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1313
Water-Compatible Iminium Catalysis

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1314
Organocatalytic Chemo- and Regioselective Acylation of Monosaccharides

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1315
Chiral β-Aminophosphine Oxides via Bicyclic Guanidine-Mediated Phospha-Michael Reaction

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1316
Asymmetric Silylation: Extension to Kinetic Resolution

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1317
Enzymatic Resolution on Ionic Acylating Agents

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1318
Desymmetrization of Meso-Aziridines

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Polymer-Supported Synthesis
1319
Ultra-Small Nano-Palladium on Giant Magnetic Nanoparticles

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1320
Heterogeneous Catalytic Asymmetric Direct Aldol Reaction in Water

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1321
Magnetic Nanoparticles-Supported Platinum Nanoparticles FREE ACCESS

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1322
Au/TiO₂-Catalyzed Aerobic Oxidation of Alcohols

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1323
Synthesis of Jasplakinolide Analogues

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1324
Immobilization of Pybox Ligand to Polystyrene Resin via Click Chemistry

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1325
Alkene Epoxidation Catalyzed by a SiO₂-Supported Ruthenium Catalyst

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1326
Highly Selective Hydroformylation of Vinylarenes to Branched Aldehydes

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1327
PS-NHC-Palladium Catalyst for Sonogashira Coupling

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1328
Solid-Phase [2+2+2] Cycloaddition of Resin-Bound Dipropargylamine with Alkynes

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1329
A Magnetically Recyclable Nanocomposite Catalyst for Olefin Epoxidation

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