Synfacts

Issue 01 · January 2014

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Synform
A1
Zanda, Matteo: SYNFORM ISSUE 2014/01 FREE ACCESS

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Synthesis of Natural Products and Potential Drugs
z1
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0001
Synthesis of (–)-Nutlin-3 FREE ACCESS

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0002
Short Total Synthesis of (±)-Mytilipin A FREE ACCESS

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0003
Total Synthesis of Indoxamycins A, C, and F FREE ACCESS

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0004
Total Synthesis of Spirotryprostatin A FREE ACCESS

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0005
Total Synthesis of (+)-Asperolide C FREE ACCESS

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0006
A Formal Synthesis of Atorvastatin FREE ACCESS

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0007
Synthesis of Levamisole FREE ACCESS

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0008
Synthesis of (+)-Fusarisetin A FREE ACCESS

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0009
Synthesis of Jerantinine E FREE ACCESS

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0010
Synthesis of Epigenetic Regulator I-BET762 (GSK525762) FREE ACCESS

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0011
Synthesis of (+)-N-Methylwelwitindolinone D Isonitrile FREE ACCESS

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0012
Synthesis of a SIRT1 Inhibitor FREE ACCESS

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Synthesis of Heterocycles
z13
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0013
Synthesis of 2-Trifluoromethylquinolines via a [2+3] Cycloaddition FREE ACCESS

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0014
Iodine-Mediated 1,3-Dipolar Cycloaddition to Benzo(f)isoindole-4,9-diones FREE ACCESS

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0015
Three-Component Synthesis of (Pyrrolo)quinazolines FREE ACCESS

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0016
Synthesis of 6-Trifluoromethyl-Phenanthridines from Diaryl Isonitriles FREE ACCESS

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0017
Synthesis of Fused Imidazole–Chromenone and –Quinolone Derivatives FREE ACCESS

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0018
C2-Substituted Indoles via Ruthenium-Catalyzed C–H Bond Functionalization FREE ACCESS

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0019
Synthesis of 1,2,3-Triazoles from N-Tosylhydrazones and Anilines FREE ACCESS

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0020
Synthesis of 5-Arylfuranones via a Carbonylative Heck Reaction FREE ACCESS

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0021
Hydroarylation Approach to Phosphacoumarins FREE ACCESS

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0022
Asymmetric Organocatalytic Synthesis of Lactams and Lactones FREE ACCESS

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0023
Polycyclic Imines via Radical Cyclization of Ene Sulfonamides FREE ACCESS

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0024
Synthesis of Phosphaisocoumarins via Ruthenium Catalysis FREE ACCESS

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0025
Three-Component Route for the Regioselective Construction of N-Arylbenzimidazoles FREE ACCESS

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0026
Construction of Spirocyclic Oxindoles for Indole Alkaloid Synthesis FREE ACCESS

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0027
Aza-Morita–Baylis–Hillman Synthesis of Benzoxazepines FREE ACCESS

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Synthesis of Materials and Unnatural Products
z29
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0029
One-Pot Synthesis of Thiepin-Fused Heteroacenes FREE ACCESS

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0030
Gold-Catalyzed Synthesis of Anthracenes FREE ACCESS

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0031
Hypervalent Iodine for α,α-Dihalogenation FREE ACCESS

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0032
Pentacenes Communicate Through Space FREE ACCESS

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0033
C–H Arylation with Platinum FREE ACCESS

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0034
Insert, Cyclize, Eliminate: Polyimides from Imidates and Isocyanates FREE ACCESS

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0035
Push–Pull Chromophores from Indan-1,3-dione FREE ACCESS

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0036
Facile Access to Heteroaromatic Triphenylene Analogues FREE ACCESS

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0037
Expanded [n]Radialenes: Unusual Carbon-Rich Molecules FREE ACCESS

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0038
Quinoxalines Directly from Electron-Deficient Alkynes FREE ACCESS

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0039
A Tubular Structural Analogue of Helicene FREE ACCESS

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0040
Superacid Anions from Tetracyanothiophene FREE ACCESS

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Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
z41
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0041
A Chiral Biaryl P,N-Ligand for Asymmetric Catalysis FREE ACCESS

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0042
Cu-Catalyzed Asymmetric 1,6-Conjugate Addition of Dialkylzinc FREE ACCESS

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0043
Arylation of Racemic Secondary Benzylic Electrophiles by Nickel Catalysis FREE ACCESS

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0044
Enantioselective Alkylation of β-Keto Esters FREE ACCESS

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0045
Rh₂(R-TPCP)₄-Catalyzed Enantioselective Syntheses of 2,5-Dihydroisoxazoles FREE ACCESS

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0046
Palladium-Catalyzed Enantioselective C–H Iodination FREE ACCESS

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0047
Ni-Catalyzed Annulation of Donor–Acceptor Oxiranes with Imines FREE ACCESS

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0048
Consecutive Intramolecular Desymmetrization and Kinetic Resolution FREE ACCESS

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0049
Enantioselective Low-Temperature 1,4-Addition of Arylboronic Acids FREE ACCESS

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0050
Rhodium-Catalyzed Enantioselective Synthesis of 1,2-Diols FREE ACCESS

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0051
Asymmetric Nickel-Catalyzed Hydrocarbamoylation of Alkenes FREE ACCESS

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0052
Enantioselective Rhodium-Catalyzed DYKAT of Racemic Allenes FREE ACCESS

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0053
Synthesis of Spiro-[Butyrolactone-Pyrrolidine] FREE ACCESS

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0054
N,N′-Dioxide–Scandium(III)-Catalyzed Asymmetric Michael Addition FREE ACCESS

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0055
Enantioselective Homologation of α-Keto Esters with α-Diazo Esters FREE ACCESS

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0056
Silver(I)–Monophosphine-Catalyzed Asymmetric Mannich Reaction FREE ACCESS

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0057
Pd-Catalyzed Asymmetric Ring Opening of Azabenzonorbornadienes FREE ACCESS

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0058
Rhodium-Catalyzed Asymmetric Transfer Hydrogenation FREE ACCESS

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0059
Ring Opening of Azabicyclic Alkenes Co-Catalyzed by Palladium and Copper FREE ACCESS

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0060
Enantioselective Hydrogenation of Chloro-Substituted Alkenyl Boronates FREE ACCESS

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0061
Catalytic Alkenylation of Neopentyl Palladium Species Using N-Tosyl Hydrazones FREE ACCESS

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0062
Oxidative Olefination of Polyfluoroarenes Catalyzed by Palladium FREE ACCESS

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0063
Asymmetric Formal Insertion of Diazo Esters into Aryl–CHO Bonds FREE ACCESS

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0064
Enantioselective Palladium-Catalyzed Allylic Dearomatization FREE ACCESS

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0065
Mukaiyama Aldol Reaction Catalyzed by Gallium(III) Triflate FREE ACCESS

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0066
Palladium-Catalyzed Asymmetric Synthesis of Phosphine Sulfonates FREE ACCESS

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0067
Enantioselective Hydrogenation of Imines Using Cooperative Catalysis FREE ACCESS

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0068
Oxazinoindoles via Gold-Catalyzed Stereoselective Cascade Reaction FREE ACCESS

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0069
Manganese-Catalyzed Enantioselective Alkene Epoxidation FREE ACCESS

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Metal-Mediated Synthesis
z71
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0071
Co/Ti Cooperative C(sp²)–C(sp²) Cross-Coupling Reactions FREE ACCESS

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0072
Palladium-Catalyzed Anti-Markovnikov Hydroalkylation of Homoallylic Alcohols FREE ACCESS

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0073
B(C₆F₅)₃-Catalyzed Transfer Hydrosilylation of Alkenes FREE ACCESS

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0074
Highly α-Regioselective 1,4-Addition of Chalcones with Prenyl Bromide FREE ACCESS

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0075
Synthesis of 2,5-Diarylated Thiophene 1,1-Dioxides FREE ACCESS

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0076
Asymmetric Lithiation Trapping of N-Boc Heterocycles FREE ACCESS

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0077
Iridium-Catalyzed Preparation of SF₅-Substituted Aryl Trifluoroborates FREE ACCESS

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0078
[¹⁸F]Trifluoromethylation of Aryl and Heteroaryl Iodides FREE ACCESS

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0079
Stereoselective Synthesis of syn-β-Hydroxy-α-vinyl Carboxylate Esters FREE ACCESS

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0080
Bismuth-Mediated Switchable Regioselective Carbometalation FREE ACCESS

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0081
Lithiation–Borylation of Secondary Alkyl Benzoates FREE ACCESS

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0082
Zn/Cu-Mediated Aminocyclopropanation FREE ACCESS

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0083
Terminal Olefin Synthesis via Reaction of Aldehydes with Allylsamarium Bromide FREE ACCESS

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0084
Synthesis of Trisubstituted Alkenylstannanes Starting from Alkynoates FREE ACCESS

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Organo- and Biocatalysis
z85
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0085
Photocatalytic Benzylic Fluorination FREE ACCESS

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0086
Isoxazolidinones via Asymmetric Decarboxylative Protonation FREE ACCESS

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0087
Brønsted Acid Catalyzed Enantioselective Indole Aza-Claisen Rearrangement FREE ACCESS

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0088
Synthesis of Pyrrolidinones via α,β-Unsaturated Acylammonium Ions FREE ACCESS

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0089
Iminophosphorane-Catalyzed Enantioselective Ketimine Nitro-Mannich Reaction FREE ACCESS

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0090
Cooperative Catalysis in Ionic [4+2] Cycloadditions FREE ACCESS

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0091
Phosphoric Acid Mediated Glycosylation and Alcohol-Chirality Recognition FREE ACCESS

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0092
Enantioselective Arylation of Enecarbamates with Quinone Imine Ketals FREE ACCESS

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0093
Organocatalytic Total Syntheses of (+)- and (–)-Trigonoliimine A FREE ACCESS

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0094
Organocatalytic Trifluoromethylthiolation of β-Keto Esters FREE ACCESS

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0095
Novel Atropisomeric Chiral Dienes in Lewis Base Organocatalysis FREE ACCESS

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Polymer-Supported Synthesis
z97
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0097
Regio- and Enantioselective Hydrogenation Using a Peptide Catalyst FREE ACCESS

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0098
Dehydrative Alkylation of 2-Methylquinoline with Alcohols Using Pt/Al₂O₃ FREE ACCESS

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0099
Cyclopropanation of α,β-Unsaturated Aldehydes with a Supported Peptide FREE ACCESS

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0100
Synthesis of Spirooxindoles Using CuFe₂O₄ Nanoparticles FREE ACCESS

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0101
Suzuki–Miyaura Coupling Using Polymer-Stabilized Pd Nanoparticles FREE ACCESS

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0102
A Heterogeneous Bifunctional Au/Pd Nanoparticle Organocatalyst FREE ACCESS

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0103
Sonogashira Coupling with Bimetallic Pd–Au Nanoparticles on Carbon FREE ACCESS

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0104
Ligand-Free C–C and C–O Cross-Couplings with Pd–ZnFe₂O₄ FREE ACCESS

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0105
Cyclic Peptide Synthesis Using Peptidyl Salicylaldehyde Esters FREE ACCESS

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0106
Cu₂O/Cu-CNTs Catalyzed the O-Arylation of Phenols with Aryl Halides FREE ACCESS

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0107
Preparation of Nitrones Using γ-Fe₂O₃@SiO₂-H₃PW₁₂O₄₀ FREE ACCESS

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0108
Oxidative Esterification of Primary Alcohols with a Pd/Bi/Te Catalyst FREE ACCESS

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Erratum
0109
Lee, J. H.; Lee, S.-G.: Iridium-Catalyzed Amination of Unsymmetrical Allyl Carbonates FREE ACCESS

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0110
Bbaij, N. R.; Wolfe, J. P.: Synthesis of Bicyclic Ureas via Palladium-Catalyzed Carboamination FREE ACCESS

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0110
Pace, V.; Castoldi, L.; Holzer, W.: Lithium-Mediated Synthesis of N-Substituted 2-Haloacetamides FREE ACCESS

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