DOI: 10.1055/s-00000131

Synfacts

Issue 01 · Volume 10 · January 2014 DOI: 10.1055/s-003-26156

Synform

A1
Zanda, Matteo: SYNFORM ISSUE 2014/01

Synthesis of Natural Products and Potential Drugs

z1
All PDFs of this category
0001
Synthesis of (–)-Nutlin-3
0002
Short Total Synthesis of (±)-Mytilipin A
0003
Total Synthesis of Indoxamycins A, C, and F
0004
Total Synthesis of Spirotryprostatin A
0005
Total Synthesis of (+)-Asperolide C
0006
A Formal Synthesis of Atorvastatin
0007
Synthesis of Levamisole
0008
Synthesis of (+)-Fusarisetin A
0009
Synthesis of Jerantinine E
0010
Synthesis of Epigenetic Regulator I-BET762 (GSK525762)
0011
Synthesis of (+)-N-Methylwelwitindolinone D Isonitrile
0012
Synthesis of a SIRT1 Inhibitor

Synthesis of Heterocycles

z13
All PDFs of this category
0013
Synthesis of 2-Trifluoromethylquinolines via a [2+3] Cycloaddition
0014
Iodine-Mediated 1,3-Dipolar Cycloaddition to Benzo(f)isoindole-4,9-diones
0015
Three-Component Synthesis of (Pyrrolo)quinazolines
0016
Synthesis of 6-Trifluoromethyl-Phenanthridines from Diaryl Isonitriles
0017
Synthesis of Fused Imidazole–Chromenone and –Quinolone Derivatives
0018
C2-Substituted Indoles via Ruthenium-Catalyzed C–H Bond Functionalization
0019
Synthesis of 1,2,3-Triazoles from N-Tosylhydrazones and Anilines
0020
Synthesis of 5-Arylfuranones via a Carbonylative Heck Reaction
0021
Hydroarylation Approach to Phosphacoumarins
0022
Asymmetric Organocatalytic Synthesis of Lactams and Lactones
0023
Polycyclic Imines via Radical Cyclization of Ene Sulfonamides
0024
Synthesis of Phosphaisocoumarins via Ruthenium Catalysis
0025
Three-Component Route for the Regioselective Construction of N-Arylbenzimidazoles
0026
Construction of Spirocyclic Oxindoles for Indole Alkaloid Synthesis
0027
Aza-Morita–Baylis–Hillman Synthesis of Benzoxazepines

Synthesis of Materials and Unnatural Products

z29
All PDFs of this category
0029
One-Pot Synthesis of Thiepin-Fused Heteroacenes
0030
Gold-Catalyzed Synthesis of Anthracenes
0031
Hypervalent Iodine for α,α-Dihalogenation
0032
Pentacenes Communicate Through Space
0033
C–H Arylation with Platinum
0034
Insert, Cyclize, Eliminate: Polyimides from Imidates and Isocyanates
0035
Push–Pull Chromophores from Indan-1,3-dione
0036
Facile Access to Heteroaromatic Triphenylene Analogues
0037
Expanded [n]Radialenes: Unusual Carbon-Rich Molecules
0038
Quinoxalines Directly from Electron-Deficient Alkynes
0039
A Tubular Structural Analogue of Helicene
0040
Superacid Anions from Tetracyanothiophene

Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions

z41
All PDFs of this category
0041
A Chiral Biaryl P,N-Ligand for Asymmetric Catalysis
0042
Cu-Catalyzed Asymmetric 1,6-Conjugate Addition of Dialkylzinc
0043
Arylation of Racemic Secondary Benzylic Electrophiles by Nickel Catalysis
0044
Enantioselective Alkylation of β-Keto Esters
0045
Rh2(R-TPCP)4-Catalyzed Enantioselective Syntheses of 2,5-Dihydroisoxazoles
0046
Palladium-Catalyzed Enantioselective C–H Iodination
0047
Ni-Catalyzed Annulation of Donor–Acceptor Oxiranes with Imines
0048
Consecutive Intramolecular Desymmetrization and Kinetic Resolution
0049
Enantioselective Low-Temperature 1,4-Addition of Arylboronic Acids
0050
Rhodium-Catalyzed Enantioselective Synthesis of 1,2-Diols
0051
Asymmetric Nickel-Catalyzed Hydrocarbamoylation of Alkenes
0052
Enantioselective Rhodium-Catalyzed DYKAT of Racemic Allenes
0053
Synthesis of Spiro-[Butyrolactone-Pyrrolidine]
0054
N,N′-Dioxide–Scandium(III)-Catalyzed Asymmetric Michael Addition
0055
Enantioselective Homologation of α-Keto Esters with α-Diazo Esters
0056
Silver(I)–Monophosphine-Catalyzed Asymmetric Mannich Reaction
0057
Pd-Catalyzed Asymmetric Ring Opening of Azabenzonorbornadienes
0058
Rhodium-Catalyzed Asymmetric Transfer Hydrogenation
0059
Ring Opening of Azabicyclic Alkenes Co-Catalyzed by Palladium and Copper
0060
Enantioselective Hydrogenation of Chloro-Substituted Alkenyl Boronates
0061
Catalytic Alkenylation of Neopentyl Palladium Species Using N-Tosyl Hydrazones
0062
Oxidative Olefination of Polyfluoroarenes Catalyzed by Palladium
0063
Asymmetric Formal Insertion of Diazo Esters into Aryl–CHO Bonds
0064
Enantioselective Palladium-Catalyzed Allylic Dearomatization
0065
Mukaiyama Aldol Reaction Catalyzed by Gallium(III) Triflate
0066
Palladium-Catalyzed Asymmetric Synthesis of Phosphine Sulfonates
0067
Enantioselective Hydrogenation of Imines Using Cooperative Catalysis
0068
Oxazinoindoles via Gold-Catalyzed Stereoselective Cascade Reaction
0069
Manganese-Catalyzed Enantioselective Alkene Epoxidation

Metal-Mediated Synthesis

z71
All PDFs of this category
0071
Co/Ti Cooperative C(sp2)–C(sp2) Cross-Coupling Reactions
0072
Palladium-Catalyzed Anti-Markovnikov Hydroalkylation of Homoallylic Alcohols
0073
B(C6F5)3-Catalyzed Transfer Hydrosilylation of Alkenes
0074
Highly α-Regioselective 1,4-Addition of Chalcones with Prenyl Bromide
0075
Synthesis of 2,5-Diarylated Thiophene 1,1-Dioxides
0076
Asymmetric Lithiation Trapping of N-Boc Heterocycles
0077
Iridium-Catalyzed Preparation of SF5-Substituted Aryl Trifluoroborates
0078
[18F]Trifluoromethylation of Aryl and Heteroaryl Iodides
0079
Stereoselective Synthesis of syn-β-Hydroxy-α-vinyl Carboxylate Esters
0080
Bismuth-Mediated Switchable Regioselective Carbometalation
0081
Lithiation–Borylation of Secondary Alkyl Benzoates
0082
Zn/Cu-Mediated Aminocyclopropanation
0083
Terminal Olefin Synthesis via Reaction of Aldehydes with Allylsamarium Bromide
0084
Synthesis of Trisubstituted Alkenylstannanes Starting from Alkynoates

Organo- and Biocatalysis

z85
All PDFs of this category
0085
Photocatalytic Benzylic Fluorination
0086
Isoxazolidinones via Asymmetric Decarboxylative Protonation
0087
Brønsted Acid Catalyzed Enantioselective Indole Aza-Claisen Rearrangement
0088
Synthesis of Pyrrolidinones via α,β-Unsaturated Acylammonium Ions
0089
Iminophosphorane-Catalyzed Enantioselective Ketimine Nitro-Mannich Reaction
0090
Cooperative Catalysis in Ionic [4+2] Cycloadditions
0091
Phosphoric Acid Mediated Glycosylation and Alcohol-Chirality Recognition
0092
Enantioselective Arylation of Enecarbamates with Quinone Imine Ketals
0093
Organocatalytic Total Syntheses of (+)- and (–)-Trigonoliimine A
0094
Organocatalytic Trifluoromethylthiolation of β-Keto Esters
0095
Novel Atropisomeric Chiral Dienes in Lewis Base Organocatalysis

Polymer-Supported Synthesis

z97
All PDFs of this category
0097
Regio- and Enantioselective Hydrogenation Using a Peptide Catalyst
0098
Dehydrative Alkylation of 2-Methylquinoline with Alcohols Using Pt/Al2O3
0099
Cyclopropanation of α,β-Unsaturated Aldehydes with a Supported Peptide
0100
Synthesis of Spirooxindoles Using CuFe2O4 Nanoparticles
0101
Suzuki–Miyaura Coupling Using Polymer-Stabilized Pd Nanoparticles
0102
A Heterogeneous Bifunctional Au/Pd Nanoparticle Organocatalyst
0103
Sonogashira Coupling with Bimetallic Pd–Au Nanoparticles on Carbon
0104
Ligand-Free C–C and C–O Cross-Couplings with Pd–ZnFe2O4
0105
Cyclic Peptide Synthesis Using Peptidyl Salicylaldehyde Esters
0106
Cu2O/Cu-CNTs Catalyzed the O-Arylation of Phenols with Aryl Halides
0107
Preparation of Nitrones Using γ-Fe2O3@SiO2-H3PW12O40
0108
Oxidative Esterification of Primary Alcohols with a Pd/Bi/Te Catalyst

Erratum

0109
Lee, J. H.; Lee, S.-G.: Iridium-Catalyzed Amination of Unsymmetrical Allyl Carbonates
0110
Bbaij, N. R.; Wolfe, J. P.: Synthesis of Bicyclic Ureas via Palladium-Catalyzed Carboamination
0110
Pace, V.; Castoldi, L.; Holzer, W.: Lithium-Mediated Synthesis of N-Substituted 2-Haloacetamides