DOI: 10.1055/s-00000131

Synfacts

Issue 09 · Volume 11 · September 2015 DOI: 10.1055/s-005-29987

Synform

A120
Zanda, Matteo: SYNFORM ISSUE 2015/09

Synthesis of Natural Products and Potential Drugs

z897
All PDFs of this category
0897
Total Synthesis of (–)-Jiadifenolide
0898
Synthesis of Phthioceranic Acid
0899
Synthesis of JAK2 Inhibitor BMS-911543
0900
Synthesis of Trichodermamides A, B, and C
0901
Synthesis of CJ-16,264
0902
Synthesis of Alisertib
0903
Total Synthesis of (–)-Amphidinolide P
0904
Synthesis of a Matrix Metalloproteinase Inhibitor
0905
Synthesis of (+)-Machaeriol B, (+)-Machaeriol D, (+)-Δ8-THC, and Analogues
0906
Synthesis of Chk1 Inhibitor GDC-0425
0907
Synthesis of (R)-Ruxolitinib
0908
Synthesis of BMS-191011
0909
Synthesis of Oridamycins A and B
0910
Chemoenzymatic Synthesis of a Rosuvastatin Building Block

Synthesis of Heterocycles

z911
All PDFs of this category
0911
Synthesis of Isoxazolino Phenanthridines
0912
Morpholines and Spirocyclic Dihydrofurans from Oxetanyl N,O-Acetals
0913
Synthesis of Dihydro-1H-benzothiazolopyridines by NHC Catalysis
0914
Azaquinolizinium Salts by Ring-Closing Metathesis
0915
Formal Hydroamination of Alkenes with Nitro- and Heteroarenes
0916
Radical-Mediated Annulations of Benzene-Linked 1,n-Enynes
0917
Optimized Process Route to a Benzoxazepine-Derived Kinase Inhibitor
0918
Metal-Free Synthesis of Perfluorinated Oxindoles
0919
Selective Synthesis of 3- or 5-Substituted Aminopyrazoles
0920
7-Azaindoles via Rhodium(III)-Catalyzed C–H Activation–Annulative Coupling
0921
Aminodifluoromethylation of Unactivated Alkenes
0922
Stereodivergent Synthesis of Substituted Tetrahydrofurans
0923
Pyrroles and Oxazines via Cycloaddition of Borodienes with Nitrosoarenes
0924
A Radical Oxidative Annulation Route to Dihydrofurans and Indolizines
0925
Synthesis of Benzazoles Catalyzed by Sodium tert-Butoxide

Synthesis of Materials and Unnatural Products

z927
All PDFs of this category
0927
New CN and CC Group-Transfer Reagents
0928
A Different Angle
0929
One Reagent, Three Reactions in One Pot
0930
Boron Goes Both Ways
0931
An All-Pnictogen Aromatic
0932
Organic Traps: Getting Hydrocarbons to Shine
0933
Two Rings to Rule Them All: Catenated Polyesters via Macrocycle Expansion
0934
A Greener Path to Bioplastics
0935
Cages Interlocked by Dynamic Metathesis
0936
Propellers with Nitrogen: New Propulsion towards 2D Polymers?
0937
A One-Step Synthesis of Chelating, Alpha-C2-Bridged Biphospholes
0938
A Scratch ‘n’ Shine Polymer

Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions

z939
All PDFs of this category
0939
Palladacycle-Catalyzed Highly Enantioselective Arylation of Sulfonylimines
0940
Rhodium-Catalyzed Asymmetric Construction of 3-Hydroxypiperidones
0941
Copper-Catalyzed Synthesis of Chiral Phosphine Boronates
0942
Iridium-Catalyzed Asymmetric Hydroalkynylation of Norbornadienes
0943
Allylic Alkylation of 3-Substituted Indoles
0944
Asymmetric Allylic Dearomatization of Pyrroles and Controllable Migration
0945
Enantioselective Copper-Catalyzed Synthesis of Lactones
0946
Enantioselective Hydroamination of Unactivated Internal Olefins
0947
Asymmetric Transformation of 3-Isothiocyanatooxindoles
0948
Copper-Catalyzed Desymmetrative Reaction Forming Chiral O-Heterocycles
0949
N,N′-Dioxide/Nickel(II)-Catalyzed Asymmetric Hetero-Diels–Alder Reaction
0950
Enantioselective Synthesis of Allenoates by Copper Catalysis
0951
Highly Efficient Asymmetric Palladium-Catalyzed Decarboxylative Allylic Alkylation
0952
Transfer Hydrogenation–Dynamic Kinetic Resolution of α-Alkoxy β-Keto Esters
0953
syn-Stereoselective Ring Opening of Oxabenzonorbornadienes
0954
Enantioselective Synthesis of Isoxazolines by 1,3-Dipolar Cycloaddition
0955
Regio- and Enantioselective Intermolecular Hydroamination of Alkynes
0956
Asymmetric Copper-Catalyzed Formal [4+3] Annulation of Cyclopropanes and Dienes
0957
Regio- and Enantioselective Redox Relay Heck Reactions
0958
Asymmetric 1,4-Addition Using a Chiral Phosphine–Olefin Ligand
0959
Cycloheptenes by a Gold-Catalyzed Tandem Alkoxylation–Claisen Rearrangement
0960
Asymmetric Hydrogenation of Fluorinated Pyrazol-5-ols
0961
Rhodium(I)-Catalyzed Enantioselective Cycloadditions
0962
Allyl–Allyl Cross-Coupling of Allylic Carbonates with (E)-1,3-Diarylpropenes
0963
Cinchona Alkaloid Amide/Zinc(II) Catalyzed Mannich Reaction of Ketimines
0964
Diastereoselective Synthesis of Chromane-4-ones
0965
Aliphatic α-Amino Acids by Rhodium-Catalyzed Asymmetric Hydrogenation
0966
Enantioselective Interrupted Feist–Bénary Reaction with Ynones
0967
Multicomponent Reaction for the Synthesis of γ-Oxo-β-amino Esters

Metal-Mediated Synthesis

z969
All PDFs of this category
0969
Directed Iron-Catalyzed C–H Methylation
0970
Spirocyclization of α-Aminonitriles
0971
α-Alkylation of α-MIDA Boryl Aldehydes
0972
Mn(OAc)3-Mediated Aerobic Oxidative Decarboxylative Coupling
0973
Iridium-Catalyzed Borylation of Benzylic C–H Bonds
0974
Palladium-Catalyzed Monofluoromethylation of Arylboronic Esters
0975
Copper-Catalyzed Reductive Alkylation of 1,3-Dienes with Alkyl Fluorides
0976
Lithiation of Azobenzenes
0977
One-Pot Unsymmetrical Ketone Synthesis
0978
Asymmetric Arylation of Amino Acids
0979
Diastereoselective Formation of Alcohols
0980
Titanium(IV)-Mediated Amination of Aryl Methyl Ethers
0981
Copper Nitrate Mediated Synthesis of Isoxazolines
0982
Chemoselective Suzuki–Miyaura Cross-Coupling
0983
Perfluoroalkyl and -aryl Zinc Ate Complexes in Synthesis

Organo- and Biocatalysis

z985
All PDFs of this category
0985
Highly Efficient and Enantioselective Silylation of Alcohols
0986
Amine-Catalyzed Conjugate Addition of Aldehydes to β-Tosyl Enones
0987
In Situ Generated N-tert-Butoxycarbonyl Imines for Mannich Reactions
0988
Organocatalytic Nazarov–Semipinacol Rearrangement Cascade
0989
Stereospecific Oxidative C–H Amination Catalyzed by Iodoarenes
0990
Asymmetric α-Cyanoalkylation of Aldehydes by Photoredox Organocatalysis
0991
Chiral Phosphoric Acid Catalyzed Nucleophilic α-Amination of Azoalkenes
0992
Asymmetric Conjugate Peroxidations of α,β-Unsaturated Aldehydes
0993
Enzymatic Oxidative Decarboxylation of Fatty Acids to 1-Alkenes
0994
Asymmetric Dearomatization of Pyridines

Polymer-Supported Synthesis

z995
All PDFs of this category
0995
Chemoselective Hydrogenation of Aldehydes on Stable Gold Nanoparticles
0996
Polymer Foam Supported Palladium Nanoparticles for Suzuki Reactions
0997
Flow Reactors Using Hollow Fibers for Acid, Base, or Chiral Rhodium Catalysis
0998
Oxidative Condensation of Aldehydes and Amines by Using Gold Nanoparticles
0999
Synthesis of Imidazoles with TFE/SBA-15-Pr-SO3H
1000
C–N Bond Formation of Secondary Amines with Cobalt/Alumina Catalyst
1001
Development of a Silica-Supported Ruthenium Bipyridyl Photocatalyst
1002
N-Arylation of Amines with Arylboronic Acids Using Supported Copper
1003
Base-Free Copper Powder-Catalyzed Knoevenagel Condensation
1004
Oxidative Amidation of Alcohols on Iron(III) Hydroxide/Magnetite Nanoparticles
1005
Controlled Aromatic Nitration with a Poly-(4-vinylpyridine)–Nitrating Mixture Complex
1006
Continuous-Flow Hydrogenation with Supported Platinum Nanoparticles
1007
Cycloisomerization of Dipeptides by Using Supported Gold Nanoparticles
1008
Solid-Phase Synthesis of γ- and δ-Lactams via N-Acyliminium Ions
1009
Reductive Alkylation by Using Calcium Hydride and Palladium on Carbon
1010
Borylation of Alkyl Bromides by Using Copper(I) Oxide Nanoparticles on Carbon Black