Synfacts

Issue 10 · October 2015

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A134
SYNFORM ISSUE 2015/10 FREE ACCESS

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Synthesis of Natural Products and Potential Drugs
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1011
Asymmetric Fluorination Approach to an SYK Inhibitor FREE ACCESS

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1012
Total Synthesis of (–)-Hosieine A

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1013
Total Synthesis of Pandamarine FREE ACCESS

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1014
Synthesis of (+)-Zincophorin Methyl Ester

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1015
Synthesis of (R)-Baclofen

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1016
Total Synthesis of Fidaxomicin

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1017
Synthesis of Axitinib

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1018
Total Synthesis of Pallambins A and B

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1019
Synthesis of AG-041 Analogues

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1020
Synthesis of OZ439

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1021
Synthesis of (R)-Lisophylline

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1022
Synthesis and Stereochemical Reassignment of Propindilactone G

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1023
Synthesis of Sonepiprazole by an Asymmetric Oxa-Michael Reaction

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1024
Synthesis of Amathaspiramides

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1025
Synthesis of a SYK Inhibitor

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1026
Propargyl-Linked Antifolates Overcome Resistance in S. aureus

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Synthesis of Heterocycles
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1027
Synthesis of Fused Imidazobenzodiazepinones by Ugi Reaction

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1028
Oxabicycles from Gold-Catalyzed Prins-Type Cyclization of Enynols

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1029
Nickel-Catalyzed Asymmetric Synthesis of Axially Chiral Isoquinolones

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1030
Enantioselective Synthesis of Chiral Fluorinated Isoindolinones

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1031
Synthesis of Oligocyclic Dienes by anti-Carbopalladation–Heck Reaction

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1032
Copper-Catalyzed Synthesis of Phosphonylated Quinoline-2,4-diones

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1033
Synthesis of Pyrazolo-triazolo[1,4]oxazepines by [2+3] Cycloaddition

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1034
Palladium-Catalyzed Synthesis of Dibenzofurans from 2-Iododiaryl Ethers

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1035
Synthesis of Pyrazoles from N-Propargyl Hydrazones Mediated by tert-BuOK

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1036
Four-Component Reaction Approach to Uracil Analogues

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1037
Lewis Acid Catalyzed Synthesis of Di/Trifluoromethyl-1,2,3,4-Tetrahydroquinazolines

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1038
Gold-Catalyzed Synthesis of 2-Aminoindoles and β-Carbolines

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1039
New Biocatalysts for the Efficient Synthesis of Enantiopure N-Heterocycles

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1040
Synthesis of 2-Azabicyclo[3.2.0]hept-2-enes and Pyrroles from Aza-enynes

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1041
Synthesis of Trisubstituted Isoxazoles from Morita–Baylis–Hillman Acetates

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Synthesis of Materials and Unnatural Products
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1043
Hand Specific Rings FREE ACCESS

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1044
Bridged Bithiophene Building Blocks

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1045
Floppy Fullerene Sandwiches

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1046
Flashing Hydrocarbons from Tetrazoles

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1047
Carbazoles Made by a Simple Swap

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1048
Azaborines Aligned: One, Two, Three, and More

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1049
Tetraphenylhexaazaanthracenes: 16π Weakly Antiaromatic Species

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1050
A New Member in the Family: Synthesis of a Pyrene Tetracarboxylic Diimide

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1051
Carb(azole)-load Your Metallodendrimers: A New Regimen

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1052
Novel Pyrene-Fused Chromophores

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1053
Hole-y Charged Polymers, Ball Mill!

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1054
Bridge the Gap with Light

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Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
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1055
Chiral γ-Lactams by Enantioselective Cyclopropane Functionalization FREE ACCESS

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1056
Asymmetric Scandium-Catalyzed Bromocyclization of N-Tosylcarbamates

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1057
Gold-Catalyzed Intramolecular Cyclopropanation of Sulfonium Ylides

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1058
Asymmetric Pd(II)-Catalyzed Cyclization of Allenyl Aldehydes with Boronic Acids

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1059
Diastereoselective Copper-Catalyzed Annulation of Hydrazones

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1060
Palladium-Catalyzed Fluorination via sp³ C–H Functionalization

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1061
Rhodium-Catalyzed Asymmetric Arylation of α-Aryl-α-diazoacetates

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1062
Ruthenium-Catalyzed Asymmetric Lactonization through Tsuji–Trost Allylation

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1063
Asymmetric Transfer Hydroformylation Using Paraformaldehyde

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1064
Iridium-Catalyzed Hydroacylation of Strained Alkenes with Salicylaldehydes

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1065
Silver-Catalyzed Asymmetric 1,3-Dipolar Cycloaddition

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1066
Enantioselective Hydroformylation of Terminal Olefins

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1067
Intermolecular Hydroarylations of Norbornenes

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1068
Diastereoselective Trifluoromethylation via Photoredox Catalysis

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1069
Scandium(III)-Catalyzed Asymmetric Opening of 2,3-Epoxy 3-Aryl Ketones

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1070
Asymmetric Alkylation of Cyclic N-Acyl Hemiaminals with Aldehydes

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1071
Iridium-Catalyzed Trichloromethylation of 2-Acylimidazoles and Pyridines

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1072
Olefin-Directed Palladium-Catalyzed Stereoselective Arylation of Allenes

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1073
Enantioselective Carbonyl (α-Cyclopropyl)-allylation via Transfer Hydrogenation

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1074
Chiral Heterocycles Using a Rhodium/Zirconium–BINOL Catalyst

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1075
Palladium-Catalyzed Asymmetric Intermolecular Heck Reaction of Dihydrofurans

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1076
Rhodium-Catalyzed Desymmetrization of α-Quaternary Centers

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1077
Asymmetric Arylation of Secondary Alkyl Electrophiles FREE ACCESS

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1078
Enantioselective Ring Opening of Azabenzonorbornadienes

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1079
Ruthenium-Catalyzed Asymmetric Allylic Alkylation

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1080
Enantioselective One-Pot Copper- and Gold-Catalyzed Alkylation and Annulation

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Metal-Mediated Synthesis
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1081
Transnitrilation of Grignard Reagents and Aryllithiums FREE ACCESS

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1082
Palladium-Catalyzed Tandem Cross-Coupling towards 9H-Fluorenes

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1083
Iron-Catalyzed Cross-Coupling of Alkenyl Acetates

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1084
Nickel-Catalyzed Alkyl–Alkyl Cross-Coupling

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1085
Allylic Alkylation of α-Amino Ketones

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1086
Catalytic Asymmetric Vinylation of Imines

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1087
Hydroxyl-Directed Cross-Coupling

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1088
Copper-Catalyzed Cross-Coupling of Allylboronic Acid Pinacol Ester with Haloalkanes

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1089
Cross-Coupling of Unactivated Trialkyl(aryl)boranes with Aryl Halides

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1090
Cobalt-Catalyzed Cross-Coupling of Piperidines with Grignard Reagents

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1091
Lithiation–Borylation–Protodeboronation Methodology

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1092
Rhodium-Catalyzed Vinylation

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1093
Mild Gold(I)-Catalyzed Protodeboronation

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1094
Nickel-Catalyzed Fluoromethylation of Arylboronic Acids

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1095
Ruthenium-Catalyzed C–O/C–N Alkenylation of Aromatic Ketones

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Organo- and Biocatalysis
z1097
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1097
Catalytic Asymmetric Umpolung of Imines

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1098
Glycosylation by Using Electron-Deficient Pyridinium Salts

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1099
NHC-Catalyzed Dimerization and Cross-Coupling of Enals to Cyclopentanones

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1100
Hydrogen Activation and Hydrogenation with Fluorophosphonium Cations

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1101
para Vinylation of Unprotected Phenols by a Biocatalytic Cascade

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1102
Asymmetric Organocatalytic Conjugate Addition of Trifluoroborates

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1103
Phosphine-Catalyzed Doubly Stereoconvergent γ-Additions to Allenoates

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1104
Sulfenate-Catalyzed Alkyne Synthesis

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Polymer-Supported Synthesis
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1105
Asymmetric Carbonyl Reduction with a Supported Ketoreductase FREE ACCESS

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1106
A Magnetic Nickel Ferrate–Glutamate–Copper Catalyst for 1,2,3-Triazole Synthesis

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1107
One-Pot Reduction–Isomerization of α,β-Unsaturated Ketones

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1108
Deoxygenative Coupling of Nitroarenes on Ceria-Supported Gold Catalysts

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1109
α-Acyloxylation of (Thio)Ethers Catalyzed by a Copper–Iron Mixed Oxide

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1110
Zinc Oxide-Supported Palladium: Cross-Coupling at ppb Catalyst Loadings

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1111
Nano Copper Ferrite-Catalyzed C–H Arylation of Benzothiazoles with Aryl Iodides

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1112
Nucleophilic Hydroxylation of Alkyl Halides by Using an Oligoglycol-Bridged Ionic Liquid

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1113
A Rasta Resin Supported Base Catalyst for the Morita–Baylis–Hillman Reaction of Allenones

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1114
Reductive N-Alkylation with Supported Rhodium Nanoparticles

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1115
Dehydrogenation of Cyclohexanones with Palladium/Carbon Under Hydrogen

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1116
Dehydrogenative Synthesis of Benzazoles with Platinum Catalysts

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1117
Supported Molybdenum-Catalyzed Oxidation of Sulfides to Sulfoxides

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1118
Pyrazoloisoquinolines and Pyrazolopyridines by Carbonaceous Sulfonic Acid Catalysis

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1119
Metal–Organic Framework-Supported Palladium Nano-Catalyst for Suzuki–Miyaura Coupling

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