Synfacts
Ausgabe 10 · Oktober 2018
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Ausgabe
Synform
A153
SYNFORM
ISSUE 2018/10
FREIER ZUGRIFF
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Synthesis of Natural Products and Potential Drugs
z0999
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PDF (448 kb)
0999
Synthesis of a Phosphoinositide 3-Kinase (PI3K) β Inhibitor
FREIER ZUGRIFF
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PDF (158 kb)
1000
Synthesis of (–)-Dendrobine, (–)-Mubironine B, and (–)-Dendroxine
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PDF (110 kb)
1001
Asymmetric Total Synthesis of (+)-Aplysiasecosterol A
FREIER ZUGRIFF
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PDF (143 kb)
1002
Synthesis of (–)-Septedine
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PDF (115 kb)
1003
Synthesis of AZD1656
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PDF (113 kb)
1004
Synthesis of (+)-Cyclocitrinol
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PDF (109 kb)
1005
Synthesis of (–)-Xishacorene B
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PDF (111 kb)
1006
Synthesis of BMS-978587
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PDF (117 kb)
1007
Synthesis of QCA570
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PDF (110 kb)
1008
Total Synthesis of (–)-Cycloclavine
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PDF (112 kb)
1009
Synthesis of Esomeprazole
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PDF (105 kb)
1010
Synthesis of GDC-0853
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PDF (118 kb)
1011
Synthesis of OV329
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PDF (132 kb)
1012
Total Synthesis of (–)-Actinophyllic Acid
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PDF (111 kb)
Synthesis of Heterocycles
z1013
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PDF (383 kb)
1013
Synthesis of Enantioenriched 1
H
/3
H
-Pyrroles and Pyrroloimidazoles
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PDF (116 kb)
1014
Indolo[3,2-
c
]coumarins and Benzofuro[3,2-
c
]quinolinones
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PDF (115 kb)
1015
Synthesis of Trifluoromethylated Pyrrolidine and Piperidine Amino Acids
FREIER ZUGRIFF
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PDF (142 kb)
1016
Hypervalent Iodine Reagent for the Synthesis of 2-Substituted Indoles
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PDF (113 kb)
1017
Phosphonium Salts as Surrogates for Aromatic Carbon–Heteroatom Bond Formation
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PDF (115 kb)
1018
Scalable Synthesis of an
exo
-Triazolylazabicycle
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PDF (108 kb)
1019
Synthesis of Cyclic Ureas by a Cross-Metathesis/Aza-Michael Sequence
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PDF (106 kb)
1020
Synthesis of Quinolines through Double-Oxidative Dehydrogenative Cyclization
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PDF (112 kb)
1021
C5 Alkenylation of Imidazoles and the Synthesis of Benzimidazoles
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PDF (107 kb)
1022
Palladium-Mediated Stereoselective Synthesis of 3,4-Fused Indolines
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PDF (113 kb)
1023
Samarium(II) Iodide Mediated Synthesis of Five- and Six-Membered N-Heterocycles
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PDF (106 kb)
1024
Silver-Mediated Synthesis of Fluorinated Oxazolidinones
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PDF (111 kb)
1025
C4-Activated Arylation of Pyrrolidines and Piperidines
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PDF (110 kb)
1026
Pyranopyrimidine–Triazole Hybrid Molecules
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PDF (117 kb)
1027
Quinoline-4-carboxylic Acids and Esters from
N
,
N
-Dimethylenaminones and Isatins
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Synthesis of Materials and Unnatural Products
z1029
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PDF (361 kb)
1029
Lucky Seven-Membered Rings in N-Doped Nonplanar Nanographenes
FREIER ZUGRIFF
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PDF (130 kb)
1030
One-Step Yamamoto Coupling of Benzophenes and Cyclooctatetraenes
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PDF (108 kb)
1031
Counting Up: One-, Two-, and Three-Boron Fused Oligo-Naphthalenes
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PDF (105 kb)
1032
No Rotation Allowed: Triply Fused Porphyrin–Nanographene Conjugates
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PDF (116 kb)
1033
All About That Strain: C–C Bond Activations of Cycloparaphenylenes by a Pt Complex
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PDF (109 kb)
1034
So Retro: Synthesis of Tribenzocarbazoles from Azapropellanes
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PDF (107 kb)
1035
To [
n
]Acenes and Beyond!
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PDF (111 kb)
1036
New End-Capping System for Solution-Processable Oligothiophenes
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PDF (111 kb)
1037
The Ramberg–Bäcklund Reaction Applied to Poly(arylene Vinylene) Synthesis
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PDF (106 kb)
1038
Diastereocontrol by Blocking Nitrogen Inversion in a Quinolino[3,2,1-
k
]Phenothiazine
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PDF (115 kb)
1039
Möbius Molecules
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PDF (107 kb)
1040
Flexibility in Macrocycles is Key for Better Electron Transport
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Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
z1041
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1041
Asymmetric Decarboxylative Allylic Alkylation of Acyclic Enol Carbonates
FREIER ZUGRIFF
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PDF (136 kb)
1042
Enantioselective Scandium-Catalyzed Formal [4+2] Cycloaddition
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PDF (113 kb)
1043
Enantioselective Intermolecular Ruthenium-Catalyzed Cycloaddition
FREIER ZUGRIFF
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PDF (138 kb)
1044
Iridium-Catalyzed Reductive Coupling of Allyl Acetates with Ynals
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PDF (108 kb)
1045
C
2
-Symmetric Chiral Biscyclosulfinamide–Olefin Ligand
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PDF (110 kb)
1046
Scandium-Catalyzed Enantioselective Ring-Opening of Cyclopropyl Ketones with Indoles
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PDF (115 kb)
1047
Asymmetric Synthesis of 2,2,3-Trisubstituted Indolines
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PDF (124 kb)
1048
Ytterbium-Catalyzed [4+2] Cycloaddition of Cyclobutenones with α
-
Keto Esters
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PDF (125 kb)
1049
Copper-Catalyzed Asymmetric Synthesis of Spirocyclic β-Lactams
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PDF (127 kb)
1050
Oxaspirocyclic Ligands for Iridium-Catalyzed Asymmetric Reduction
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PDF (116 kb)
1051
Enantioselective Ruthenium(II)-NHC Catalyzed Hydrogenation of 2-Oxazolones
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PDF (110 kb)
1052
Copper-Catalyzed Synthesis of Enantioenriched 1,2-Hydroxyboronates
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PDF (120 kb)
1053
Iridium/Copper-Catalyzed Asymmetric Radical Cyanoalkylation of Styrenes
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PDF (108 kb)
1054
Palladium–Amine-Catalyzed Enantioselective α-Allylation of Ketones
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PDF (128 kb)
1055
Cobalt-Catalyzed Enantioselective Nazarov Cyclization/Fluorination Cascade
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PDF (108 kb)
1056
Enantioselective Synthesis of Spirooxindole-thiaindans by Cooperative Catalysis
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PDF (116 kb)
1057
Gold-Catalyzed Stereoselective Synthesis of β-Fluoro Michael Acceptors
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PDF (121 kb)
1058
Reductive Asymmetric Ring-Opening of Azabenzonorbornadienes
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PDF (105 kb)
1059
Enantioselective Transfer Hydrogenation of Alkynyl Ketones
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PDF (101 kb)
1060
Asymmetric Heck–Matsuda Carbonylation
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PDF (110 kb)
1061
Fluoroalkylamines as Nucleophiles in Iridium-Catalyzed Ring Opening
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PDF (106 kb)
1062
Palladium-Catalyzed Asymmetric [4+2] Cycloaddition
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PDF (112 kb)
1063
Asymmetric Dearomative [3+2] Cycloaddition by Zinc Catalysis
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PDF (117 kb)
1064
Catalytic Diastereoselective Multi-Component Cyclopropanation
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PDF (102 kb)
1065
Palladium-Catalyzed Asymmetric Rearrangement of Allyl Enol Ethers
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PDF (105 kb)
1066
Enantioselective Iridium-Catalyzed Vinylogous Allylic Alkylation of Coumarins
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PDF (109 kb)
1067
Diastereoselective Intermolecular Semipinacol Rearrangement
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PDF (106 kb)
1068
Rhodium-Catalyzed Asymmetric Synthesis of Tertiary α-Hydroxy Esters
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PDF (126 kb)
1069
Enantioselecitve [3+2] Cycloaddition of Aurones with Isocyanoacetates
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PDF (106 kb)
1070
Palladium-Catalyzed Enantioselective Allylic C–H Alkylation of 1,4-Pentadienes
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PDF (113 kb)
Metal-Mediated Synthesis
z1071
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PDF (333 kb)
1071
Asymmetric Synthesis of Vinyl Aziridines
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PDF (107 kb)
1072
Intramolecular Glycosyl Stille Cross-Coupling
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PDF (107 kb)
1073
meta
-Arylation of Fluoroarenes
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PDF (111 kb)
1074
Redox-Neutral C–H Olefination Catalyzed by Manganese
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PDF (106 kb)
1075
Direct Reaction of Grignard Reagents with Isocyanates in Flow
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PDF (101 kb)
1076
Transition-Metal-Free Amination and Etherification of Aryl Alkyl Thioethers
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PDF (102 kb)
1077
Iron–Nickel Dual-Catalytic Olefin Functionalization
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PDF (103 kb)
1078
Mechanochemical Generation of Organozinc Compounds
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PDF (104 kb)
1079
Copper-Catalyzed Trifluoromethylation of Alkyl Iodides
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HTML
PDF (99 kb)
1080
Selective Monomethylation of Arylacetonitriles and Arylacetamides
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HTML
PDF (104 kb)
1081
Cobalt-Catalyzed Ring-Opening Coupling of Cyclopropanols with Alkynes
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HTML
PDF (104 kb)
1082
Copper Iminoarylsulfonate Complex Catalyzed Amination
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PDF (104 kb)
1083
Diastereodivergent Hydroarylation of Terminal Alkynes
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PDF (112 kb)
1084
Generation of Strained Azacyclic Allenes for Diels–Alder Cycloadditions
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PDF (108 kb)
1085
Defluoroalkylation of
gem
-Difluoroalkenes via Zinc
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PDF (112 kb)
Organo- and Biocatalysis
z1087
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PDF (338 kb)
1087
Dynamic Kinetic Resolution of Azlactones with a Chiral DMAP Catalyst
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HTML
PDF (111 kb)
1088
Acid-Catalyzed Rearrangement of Hydroxylated Pinene Derivatives
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PDF (114 kb)
1089
Activating Ketones with Low Catalyst Loadings of a Potent Chiral Lewis Acid
FREIER ZUGRIFF
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HTML
PDF (140 kb)
1090
Phosphoric Acid Catalyzed Aldehyde Addition to
o
-Quinone Methides
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HTML
PDF (114 kb)
1091
Enantioconvergent Biocatalytic Redoxisomerization of Pyranones
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PDF (116 kb)
1092
Triazolium-Salt-Catalyzed Dialkylation of Bisoxindoles
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PDF (114 kb)
1093
Enzymatic Control of the Stereochemical Course of [4+2] Cycloaddition
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PDF (112 kb)
1094
Chiral-Aldehyde-Catalyzed α-Functionalization of Glycine Esters
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HTML
PDF (132 kb)
1095
Fluorobissulfonylmethyl Iodides as Lewis Acid Catalysts
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HTML
PDF (115 kb)
1096
Biocatalytic Production of Linear α-Olefins from Carboxylic Acids
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HTML
PDF (115 kb)
Polymer-Supported Synthesis
z1097
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Volltext
PDF (287 kb)
1097
Formylation of Amines with CO
2
Using a Polymeric Frustrated Lewis Pair
FREIER ZUGRIFF
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HTML
PDF (135 kb)
1098
Hf-Based Metal–Organic Framework-Catalyzed Aldol Condensation and Hydrogenation
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HTML
PDF (106 kb)
1099
Amidation of Amines with Carboxylic Acids Catalyzed by a Metal–Organic Framework
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HTML
PDF (103 kb)
1100
Transfer Hydrogenation of Nitroarenes on Carbon-Coated Cobalt Nanoparticles
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HTML
PDF (102 kb)
1101
Photocatalytic Deoxygenation of Sulfoxides and Pyridine
N
-Oxides
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HTML
PDF (108 kb)
1102
Cyclic Carbonates from CO
2
and Epoxides on a Supported Imidazole Catalyst
Volltext
HTML
PDF (107 kb)
1103
1,4-Addition of Grignard Reagents to Chalcones on MS 4Å-Supported CuCl
2
Volltext
HTML
PDF (107 kb)
1104
Suzuki–Miyaura Coupling on Water-Soluble Fullerene-Supported PdCl
2
Volltext
HTML
PDF (106 kb)
1105
Controlled Hydrogenation of Alkynes on Bimetallic Gold/Palladium Nanoparticles
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HTML
PDF (108 kb)
1106
Ring-Opening Diborylation of Cyclopropanes on Nanoporous Gold
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PDF (104 kb)
1107
Synthesis of Symmetric Carboxylic Anhydrides from Aldehydes on a Cu-MOF
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PDF (104 kb)
Addendum
1108
Hydrogen-Bonding Phase-Transfer Catalyst Enabled Asymmetric Fluorination
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PDF (96 kb)
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