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Synfacts 2011(12): 1320-1320
DOI: 10.1055/s-0031-1289363
DOI: 10.1055/s-0031-1289363
Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
© Georg Thieme Verlag
Stuttgart ˙ New York
Hydroamination of Dienes by Gold(I)/Menthol Cooperative Catalysis
O. Kanno, W. Kuriyama, Z. J. Wang, F. D. Toste*
University of California at Berkeley, USA
Further Information
Publication History
Publication Date:
18 November 2011 (online)
Significance
The first example of Lewis acid activated Brønsted acidity in gold(I) catalysis is reported. Through a phosphine gold(I)/menthol catalyzed enantioselective diene hydroamination, pyrrolidine and piperidine adducts are formed in good yields.