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Synfacts 2009(2): 0188-0188
DOI: 10.1055/s-0028-1087640
DOI: 10.1055/s-0028-1087640
Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
© Georg Thieme Verlag
Stuttgart ˙ New York
A Protocol for Palladium(II)-Mediated Alkoxycarbonylation
Z. Li, Y. Gao, Z. Jiao, N. Wu, D. Z. Wang*, Z. Yang*
Shenzhen Graduate School of Peking University and Peking University, P. R. of China
Weitere Informationen
Publikationsverlauf
Publikationsdatum:
22. Januar 2009 (online)
Significance
The authors report an improved protocol for the palladium-mediated carbonylative annulation first put forth by Semmelhack and co-workers (J. Am. Chem. Soc. 1983, 105, 2034). With this protocol the authors have remedied certain substrate dependant challenges, allowing for a broader scope, improved yields and higher selectivity (Org. Lett. 2008, 10, 3017).