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Synfacts 2010(6): 0681-0681
DOI: 10.1055/s-0029-1219868
DOI: 10.1055/s-0029-1219868
Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
© Georg Thieme Verlag
Stuttgart ˙ New York
Enantioselective 1,3-Dipolar Cycloaddition of Azomethine Imines
T. Hashimoto, Y. Maeda, M. Omote, H. Nakatsu, K. Maruoka*
Kyoto University, Japan
Weitere Informationen
Publikationsverlauf
Publikationsdatum:
20. Mai 2010 (online)
![](https://www.thieme-connect.de/media/synfacts/201006/lookinside/thumbnails/10.1055-s-0029-1219868-1.jpg)
Significance
Building upon previous work in the area of titanium-catalyzed asymmetric [3+2] cycloadditions the authors report a highly stereoselective cycloaddition of azomethine imines, generating interesting heterocyclic compounds. Azomethine imines of type 1 have enjoyed widespread use in the literature as 1,3-dipoles; however, azomethine imines of type 3 have received little attention and have not been previously utilized in asymmetric cycloadditions. The authors have expanded the scope of cycloadditions involving azomethine imines.