Synthesis of 1,3-syn-Diol Acetals
via Re-Catalyzed Allylic Alcohol Transposition

A. T. Herrmann; T. Saito; C. E. Stivala; J. Tom; A. Zakarian

doi:10.1055/s-0030-1257819

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Synfacts 2010(8): 0915-0915
DOI: 10.1055/s-0030-1257819

Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions

Synthesis of 1,3-syn-Diol Acetals via Re-Catalyzed Allylic Alcohol Transposition

Contributor(s): Hisashi Yamamoto, Zhi Li
A. T. Herrmann, T. Saito, C. E. Stivala, J. Tom, A. Zakarian*
University of California, Santa Barbara, USA

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Publikationsverlauf

Publikationsdatum:
22. Juli 2010 (online)

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Significance

The synthesis of 1,3-syn-diol moieties has been extensively studied in organic synthesis, because they frequently appear in natural molecules. This work featured a very unique rhenium-catalyzed synthesis of 1,3-syn-diol acetals in high diastereoselectivities.